Heterocyclic carbenes: Synthesis and coordination chemistry

被引：2553

作者：

Hahn, F. Ekkehardt ^{[1
]}

Jahnke, Mareike C. ^{[1
]}

机构：

[1] Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 17期

关键词：

azolium salts; carbene complexes; heterocyclic carbenes; macrocycles; template syntheses;

D O I：

10.1002/anie.200703883

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chemistry of heterocyclic carbenes has experienced a rapid development over the last years. In addition to the imidazolin-2-ylidenes, a large number of cyclic diaminocarbenes with different ring sizes have been described. Aside from diaminocarbenes, P-heterocyclic carbenes, and derivatives with only one, or even no heteroatom within the carbene ring are known. New methods for the synthesis of complexes with N-heterocyclic carbene ligands such as the oxidative addition or the metal atom template controlled cyclization of β-functionalized isocyanides have been developed recently. This review summarizes the new developments regarding the synthesis of N-heterocyclic carbenes and their metal complexes. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3122 / 3172

页数：51

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