Heterocyclic carbenes: Synthesis and coordination chemistry

被引：2553
作者：
Hahn, F. Ekkehardt [1 ]
Jahnke, Mareike C. [1 ]
机构：
[1] Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 17期
关键词：
azolium salts; carbene complexes; heterocyclic carbenes; macrocycles; template syntheses;
D O I：
10.1002/anie.200703883
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The chemistry of heterocyclic carbenes has experienced a rapid development over the last years. In addition to the imidazolin-2-ylidenes, a large number of cyclic diaminocarbenes with different ring sizes have been described. Aside from diaminocarbenes, P-heterocyclic carbenes, and derivatives with only one, or even no heteroatom within the carbene ring are known. New methods for the synthesis of complexes with N-heterocyclic carbene ligands such as the oxidative addition or the metal atom template controlled cyclization of β-functionalized isocyanides have been developed recently. This review summarizes the new developments regarding the synthesis of N-heterocyclic carbenes and their metal complexes. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：3122 / 3172
页数：51
相关论文
共 693 条
[1]   Synthesis, structure and stability of new Pt(II)-bis(N-heterocyclic carbene) complexes [J].
Ahrens, S ;
Herdtweek, E ;
Goutal, S ;
Strassner, T .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (06) :1268-1274
[2]   Titanium N-heterocyclic carbene complexes incorporating an imidazolium-linked bis(phenol) [J].
Aihara, H ;
Matsuo, T ;
Kawaguchi, H .
CHEMICAL COMMUNICATIONS, 2003, (17) :2204-2205
[3]  
Albrecht M, 2001, ANGEW CHEM INT EDIT, V40, P3750, DOI 10.1002/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO
[4]  
2-6
[5]  
Albrecht M., 2001, ANGEW CHEM, V113, P3866, DOI DOI 10.1002/1521-3773(20011015)113:20<3866::AID-ANGE3866>3.0.C0
[6]  
2-Y
[7]   Hydrogen bonded driven anion binding by dicationic [14]imidazoliophanes [J].
Alcalde, E ;
Alvarez-Rúa, C ;
García-Granda, S ;
García-Rodriguez, E ;
Mesquida, N ;
Pérez-García, L .
CHEMICAL COMMUNICATIONS, 1999, (03) :295-296
[8]   Imidazo[1,5-a]pyridine:: A versatile architecture for stable N-heterocyclic carbenes [J].
Alcarazo, M ;
Roseblade, SJ ;
Cowley, AR ;
Fernández, R ;
Brown, JM ;
Lassaletta, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (10) :3290-3291
[9]   1,3-bis(N,N-dialkylamino)imidazolin-2-ylidenes:: Synthesis and reactivity of a new family of stable N-heterocyclic carbenes [J].
Alcarazo, M ;
Roseblade, SJ ;
Alonso, E ;
Fernández, R ;
Alvarez, E ;
Lahoz, FJ ;
Lassaletta, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (41) :13242-13243
[10]   When and how do diaminocarbenes dimerize? [J].
Alder, RW ;
Blake, ME ;
Chaker, L ;
Harvey, JN ;
Paolini, F ;
Schütz, J .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (44) :5896-5911
12345678910