C-N and C-S Bond Forming Cross Coupling in Water with Amphiphilic Resin-supported Palladium Complexes

被引：18
|
作者：
Hirai, Yoshinori [1 ,2 ]
Uozumi, Yasuhiro [1 ]
机构：
[1] Inst Mol Sci, Okazaki, Aichi 4448787, Japan
[2] KANEKA Corp, Frontier Biochem & Med Res Labs, Takasago, Hyogo 6768688, Japan
来源：
CHEMISTRY LETTERS | 2011年 / 40卷 / 09期
关键词：
ORGANIC-SYNTHESIS; CATALYST; SONOGASHIRA; SUZUKI; HECK;
D O I：
10.1246/cl.2011.934
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Catalytic C-N and C-S bond forming reactions of haloarenes with secondary amines and benzenethiols were achieved in water under heterogeneous conditions by the use of immobilized palladium complexes coordinated with the amphiphilic polystyrene-poly(ethylene glycol) resin-supported di(tert-butyl)phosphane ligand to afford aryl(dialkyl)amines and diaryl sulfides in high yield.
引用
收藏
页码：934 / 935
页数：2
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