Development of Graphene-based Materials for Lithium-Sulfur Batteries

被引:34
作者
Chen Ke [1 ,2 ]
Sun Zhenhua [1 ]
Fang Ruopian [1 ]
Li Feng [1 ]
Cheng Huiming [1 ,3 ]
机构
[1] Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China
[2] Shanghai Tech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China
[3] Tsinghua Univ, Tsinghua Berkeley Shenzhen Inst, Shenzhen 518055, Guangdong, Peoples R China
基金
中国国家自然科学基金; 国家重点研发计划;
关键词
Lithium sulfur battery; Graphene; Doping; Functionalization; Composites; LI-S BATTERIES; NITROGEN-DOPED GRAPHENE; METAL-ORGANIC FRAMEWORK; HOLLOW CARBON SPHERES; FEW-LAYER GRAPHENE; CATHODE MATERIAL; POROUS-GRAPHENE; CYCLING STABILITY; FACILE SYNTHESIS; DUAL-PROTECTION;
D O I
10.3866/PKU.WHXB201709001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Lithium-sulfur (Li-S) batteries are promising electrochemical energy storage systems because of their high theoretical energy density, natural abundance, and environmental benignity. However, several problems such as the insulating nature of sulfur, high solubility of polysulfides, large volume variation of the sulfur cathode, and safety concerns regarding the lithium anode hinder the commercialization of Li-S batteries. Graphene-based materials, with advantages such as high conductivity and good flexibility, have shown effectiveness in realizing Li-S batteries with high energy density and high stability. These materials can be used as the cathode matrix, separator coating layer, and anode protection layer. In this review, the recent progress of graphene-based materials used in Li-S batteries, including graphene, functionalized graphene, heteroatom-doped graphene, and graphene-based composites, has been summarized. And perspectives regarding the development trend of graphene-based materials for Li-S batteries have been discussed.
引用
收藏
页码:377 / 390
页数:14
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