Temperature-dependent stability of energy storage properties of Pb0.97La0.02(Zr0.58Sn0.335Ti0.085)O3 antiferroelectric ceramics for pulse power capacitors

被引:207
作者
Liu, Zhen [1 ]
Chen, Xuefeng [1 ]
Peng, Wei [1 ]
Xu, Chenhong [1 ]
Dong, Xianlin [1 ]
Cao, Fei [1 ]
Wang, Genshui [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Funct Mat & Devices, Shanghai 200050, Peoples R China
关键词
PERFORMANCE; DENSITY;
D O I
10.1063/1.4923373
中图分类号
O59 [应用物理学];
学科分类号
摘要
The dielectric properties and electrical hysteresis behaviors of Pb0.97La0.02(Zr0.58Sn0.335Ti0.085)O-3 antiferroelectric (AFE) ceramics were investigated in this work with an emphasis on energy storage properties. Three phase transition points can be detected as temperature increases. AFE and paraelectric phases are found to coexist from 100 degrees C to 170 degrees C. The room temperature recoverable energy density is 1.37 J/cm(3) at 8.6 kV/mm. With increasing temperature (from 20 degrees C to 100 degrees C) and frequency (from 0.01 to 100 Hz) under 8.6 kV/mm, the variation of recoverable energy density was less than 15%, all higher than 1.2 J/cm(3). All the corresponding energy efficiencies were no less than 75%. The high energy density, high energy efficiency, and their weak dependence on temperature and frequency during a wide scope indicate that these antiferroelectric ceramics are quite promising to be used for pulse power capacitors applications. (C) 2015 AIP Publishing LLC.
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页数:4
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