Structure and spin crossover in an iron(II) compound with tris(pyrazol-1-yl)methane and the complex Eu(dipic)2(Hdipic)]2- anion

被引：3

作者：

Shakirova, O. G. ^{[1
]}

Lavrenova, L. G. ^{[2
,3
]}

Korotaev, E. V. ^{[2
]}

Kuratieva, N. V. ^{[2
,3
]}

Kolokolov, F. A. ^{[4
]}

Burdukov, A. B. ^{[2
]}

机构：

[1] Komsomolsk On Amur State Tech Univ, Komsomolsk On Amur, Khabarovsk Krai, Russia

[2] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[3] Novosibirsk Natl Res State Univ, Novosibirsk, Russia

[4] Kuban State Univ, Krasnodar, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2016年 / 57卷 / 03期

关键词：

coordination compound; iron(II); tris(pyrazol-1-yl)methane; complex [Eu(dipic)(2)(Hdipic)](2-) anion; spin crossover; thermochromism; TRANSITION MOLECULAR MATERIALS; TEMPERATURE; LIGANDS; CRYSTAL; STATE;

D O I：

10.1134/S0022476616030082

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An iron(II) complex with tris(pyrazol-1-yl)methane (HC(Pz)(3)) of the composition [Fe(HC(Pz)(3)))(2)]center dot[Eu(dipic)(2)(Hdipic)]center dot 2H(2)O, containing an outer-sphere complex anion, is synthesized. The compound is examined by single crystal and powder X-ray diffraction, UV-Vis and IR spectroscopies, and static magnetic susceptibility. The investigation of the temperature dependence chi(T) in the temperature range 80-470 K reveals that the polycrystalline phase of the compound undergoes spin-crossover (1) D (1) a double dagger" D-5 cent(2). The transition is accompanied by thermochromism (color change pink a double dagger" white).

引用

页码：471 / 477

页数：7

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