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Indium salt-promoted organic reactions
被引:102
作者:
Fringuelli, F
[1
]
Piermatti, O
[1
]
Pizzo, F
[1
]
Vaccaro, L
[1
]
机构:
[1] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy
关键词:
D O I:
10.2174/1385272033486251
中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
The use of indium salts as catalysts and mediators in addition, cyclization, aromatic electrophilic substitution, nucleophilic substitution, coupling, reduction, rearrangement and polymerization reactions that have appeared in papers published between 2000 and the First half of 2002 is reviewed. InCl3, InBr3, InI3, InCl, InBr, InI, In(OTf)(3), and In(NTf)(3) are most commonly used indium salts depending on the reaction type and reaction conditions. The use of indium salts, generally, allows the reaction to be carried out under mild conditions, with high yield and high selectivity. Sometimes, an aqueous medium can be Used and the catalyst can be reused.
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页码:1661 / 1689
页数:29
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