Tracer diffusion in crowded narrow channels

被引:52
作者
Benichou, O. [1 ]
Illien, P. [2 ]
Oshanin, G. [1 ]
Sarracino, A. [3 ,4 ,5 ]
Voituriez, R. [1 ,6 ]
机构
[1] Sorbonne Univ, CNRS, UMR 7600, Lab Phys Theor Matiere Condensee, 4 Pl Jussieu, F-75252 Paris 05, France
[2] PSL Res Univ, ESPCI Paris, UMR Gulliver 7083, 10 Rue Vauquelin, F-75005 Paris, France
[3] Univ Sapienza Roma, ISC, CNR, Piazzale Aldo Moro 2, I-00185 Rome, Italy
[4] Univ Sapienza Roma, Dipartimento Fis, Piazzale Aldo Moro 2, I-00185 Rome, Italy
[5] Univ Campania Luigi Vanvitelli, Dipartimento Ingn, I-81031 Aversa, CE, Italy
[6] Sorbonne Univ, CNRS, UMR 8237, Lab Jean Perrin, 4 Pl Jussieu, F-75005 Paris, France
关键词
lattice gases; stochastic dynamics; tracer diffusion; narrow channels; SINGLE-FILE DIFFUSION; DENSE ADSORBED LAYER; RANDOM-WALK; CONCENTRATED LATTICE; ACTIVE MICRORHEOLOGY; BIASED DIFFUSION; PARTICLE MOTION; SELF-DIFFUSION; TRANSPORT; MODEL;
D O I
10.1088/1361-648X/aae13a
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We summarise different results on the diffusion of a tracer particle in lattice gases of hard-core particles with stochastic dynamics, which are confined to narrow channels-single-files, comb-like structures and quasi-one-dimensional channels with the width equal to several particle diameters. We show that in such geometries a surprisingly rich, sometimes even counter-intuitive, behaviour emerges, which is absent in unbounded systems. This is well-documented for the anomalous diffusion in single-files. Less known is the anomalous dynamics of a tracer particle in crowded branching single-files-comb-like structures, where several kinds of anomalous regimes take place. In narrow channels, which are broader than single-files, one encounters a wealth of anomalous behaviours in the case where the tracer particle is subject to a regular external bias: here, one observes an anomaly in the temporal evolution of the tracer particle velocity, super-diffusive at transient stages, and ultimately a giant diffusive broadening of fluctuations in the position of the tracer particle, as well as spectacular multi-tracer effects of self-clogging of narrow channels. Interactions between a biased tracer particle and a confined crowded environment also produce peculiar patterns in the out-of-equilibrium distribution of the environment particles, very different from the ones appearing in unbounded systems. For moderately dense systems, a surprising effect of a negative differential mobility takes place, such that the velocity of a biased tracer particle can be a non-monotonic function of the force. In some parameter ranges, both the velocity and the diffusion coefficient of a biased tracer particle can be non-monotonic functions of the density. We also survey different results obtained for a tracer particle diffusion in unbounded systems, which will permit a reader to have an exhaustively broad picture of the tracer diffusion in crowded environments.
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页数:19
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