Mn(salen)-catalyzed enantioselective C-H amination

被引：136
|
作者：
Kohmura, Y [1 ]
Katsuki, T [1 ]
机构：
[1] Kyushu Univ 33, JST, CREST, Fac Sci,Dept Chem,Higashi Ku, Fukuoka 8128581, Japan
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 19期
关键词：
(salen)manganese(III) complex; asymmetric C-H amination; benzylic amination; allylic amination;
D O I：
10.1016/S0040-4039(01)00427-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A chiral 3.3',5,5'-tetrabromosubstituted (salen)manganese(III) complex was found to be an efficient catalyst for asymmetric Cn amination (up to 89% ee). In the reaction of cycloalkenes, allylic amination occurred in preference to aziridination, (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：3339 / 3342
页数：4
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