A simple route to high performance nanometric metallic materials for Li-ion batteries involving the use of cellulose:: The case of Sb

A facile method for obtaining nanometric Sb particles that perform well as electrode in lithium cells is proposed. The method involves reducing SbCl(3) with NaBH(4) in solution and in the presence of commercial cellulose fibers. Once dry, the resulting composite requires no additive for use in lithium cells, where it delivers high capacity values (ca. 470 mAh g(-1)) after the first few cycles. We believe that cellulose acts as a buffer alleviating the mechanical stress to which the element is subject during the lithium insertion/de-insertion process. In fact, an electrode made from nanometric Sb prepared in the absence of cellulose was found to perform poorly; thus the capacity delivered after the fifteenth cycle was below 100 mAh g(-1). (C) 2007 Elsevier B.V. All rights reserved.