The Oxidation of Methane at Low Temperatures Over Zirconia-Supported Pd, Ir and Pt Catalysts and Deactivation by Sulfur Poisoning

被引：39

作者：

Ohtsuka, Hirofumi ^{[1
]}

机构：

[1] Osaka Gas Co Ltd, Energy Technol Labs, Konohana Ku, Osaka 5540051, Japan

来源：

CATALYSIS LETTERS | 2011年 / 141卷 / 03期

关键词：

Platinum; Iridium; Methane; Catalytic oxidation; X-ray absorption fine structure; COMBUSTION; PLATINUM; EMISSIONS; ABATEMENT; PT/AL2O3; WATER; OXIDE;

D O I：

10.1007/s10562-010-0506-x

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of methane over zirconia-supported Pd, Ir, and Pt catalysts at low temperatures under an oxidizing atmosphere and the effect of SO2 on this reaction were investigated. An Ir-Pt/ZrO2 catalyst exhibited high activity and low deactivation by SO2. Characterization of the catalyst indicated the presence of a highly oxidized Pt species that was stabilized by the addition of Ir.

引用

页码：413 / 419

页数：7

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