A novel three-dimensional hybrid framework based on fishbone-like copper halide inorganic units

被引:12
作者
Bai, XL [1 ]
Li, YG [1 ]
Wang, EB [1 ]
Xu, L [1 ]
机构
[1] NE Normal Univ, Dept Chem, Inst Polyometalate Chem, Changchun 130024, Peoples R China
基金
中国国家自然科学基金;
关键词
hydrothermal synthesis; crystal structure; copper chloride; isonicotinate;
D O I
10.1016/j.ica.2005.02.013
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel inorganic-organic hybrid cuprous chloride, (Cu2Cl)-Cl-1(IN) (IN- = isonicotinate ion) 1, has been hydrothermally synthe- sized and structurally characterized by the elemental analyses, IR spectrum, TG analysis and the single crystal X-ray diffraction. The structure of I exhibits a three-dimensional network built up from unusual fishbone-like copper(l) chloride ribbons bridged by linear isonicotinato ligands. Its luminescent property was also investigated. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:2571 / 2574
页数:4
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