A novel three-dimensional hybrid framework based on fishbone-like copper halide inorganic units

被引：12

作者：

Bai, XL ^{[1
]}

Li, YG ^{[1
]}

Wang, EB ^{[1
]}

Xu, L ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyometalate Chem, Changchun 130024, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2005年 / 358卷 / 08期

基金：

中国国家自然科学基金;

关键词：

hydrothermal synthesis; crystal structure; copper chloride; isonicotinate;

D O I：

10.1016/j.ica.2005.02.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel inorganic-organic hybrid cuprous chloride, (Cu2Cl)-Cl-1(IN) (IN- = isonicotinate ion) 1, has been hydrothermally synthe- sized and structurally characterized by the elemental analyses, IR spectrum, TG analysis and the single crystal X-ray diffraction. The structure of I exhibits a three-dimensional network built up from unusual fishbone-like copper(l) chloride ribbons bridged by linear isonicotinato ligands. Its luminescent property was also investigated. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：2571 / 2574

页数：4

共 29 条

[1] THERMOCHROMIC PHASE-TRANSITIONS IN TRANSITION-METAL SALTS [J].

BLOOMQUIST, DR ;

WILLETT, RD .

COORDINATION CHEMISTRY REVIEWS, 1982, 47 (1-2) :125-164

[2] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores [J].

Chen, BL ;

Eddaoudi, M ;

Hyde, ST ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2001, 291 (5506) :1021-1023

[3] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[4] Interpenetration in [Cd(isonicotinate)2(1,2-bis(4-pyridyl)ethane)0.5(H2O)]n, a novel octahedral polymer containing an unusual two-dimensional bilayer motif generated by self-assembly of rectangle building blocks [J].

Fu, ZY ;

Wu, XT ;

Dai, JC ;

Wu, LM ;

Cui, CP ;

Hu, SM .

CHEMICAL COMMUNICATIONS, 2001, (18) :1856-1857

[5] Heterobinuclear complexes as building blocks in designing extended structures [J].

Gheorghe, R ;

Andruh, M ;

Müller, A ;

Schmidtmann, M .

INORGANIC CHEMISTRY, 2002, 41 (21) :5314-5316

[6] Three coordinate copper(I) complexes.: Synthesis, spectral, and structural study of copper(I) complexes of 4-benzoylpyridine and X-ray crystal structure of the dimer [CuCl(4-benzoylpyridine)]2 [J].

Goher, MAS ;

Mak, TCW .

POLYHEDRON, 1998, 17 (20) :3485-3494

[7] Organic/inorganic composite materials:: Hydrothermal syntheses and structures of the one-, two-, and three-dimensional copper(II) sulfate organodiamine phases [Cu(H2O)3(4,4′-bipyridine)(SO4)]•2H2O, [Cu(bpe)2][Cu(bpe)(H2O)2(SO4)2]•2H2O, and [Cu(bpe)(H2O)(SO4)] (bpe = trans-1,2-bis(4-pyridyl)ethylene) [J].

Hagrman, D ;

Hammond, RP ;

Haushalter, R ;

Zubieta, J .

CHEMISTRY OF MATERIALS, 1998, 10 (08) :2091-2100

[8] Investigations of the copper bromide-2,2′-dipyridyl system:: Hydrothermal synthesis and structural characterization of molecular Cu3Br4(C10H8N2)2, one-dimensional CuBr2(C10H8N2), and two-dimensional [Cu2(OH)2(C10H8N2)2][Cu4Br6] [J].

Hammond, RP ;

Cavaluzzi, M ;

Haushalter, RC ;

Zubieta, JA .

INORGANIC CHEMISTRY, 1999, 38 (06) :1288-1292

[9] A novel ligand-unsupported 3D framework polymer of trimeric copper(I)) and its NLO property [J].

Kang, Y ;

Yao, YG ;

Qin, YY ;

Zhang, J ;

Chen, YB ;

Li, ZJ ;

Wen, YH ;

Cheng, JK ;

Hu, RF .

CHEMICAL COMMUNICATIONS, 2004, (09) :1046-1047

[10] Design and synthesis of an exceptionally stable and highly porous metal-organic framework [J].

Li, H ;

Eddaoudi, M ;

O'Keeffe, M ;

Yaghi, OM .

NATURE, 1999, 402 (6759) :276-279

← 1 2 3 →