High-performance effective metal-organic frameworks for electrochemical applications

被引：72
作者：
Abdelkareem, Mohammad Ali [1 ,2 ,3 ]
Abbas, Qaisar [1 ,2 ,4 ]
Mouselly, Maryam [1 ]
Alawadhi, Hussain [1 ,5 ]
Olabi, A. G. [1 ,2 ,6 ]
机构：
[1] Univ Sharjah, Ctr Adv Mat Res, Sharjah 27272, U Arab Emirates
[2] Univ Sharjah, Dept Sustainable & Renewable Energy Engn, Sharjah 27272, U Arab Emirates
[3] Minia Univ, Chem Engn Dept, Elminia, Egypt
[4] Univ West Scotland, Sch Engn Comp & Phys Sci, Inst Engn & Energy Technol IEET, Paisley PA1 2BE, Renfrew, Scotland
[5] Univ Sharjah, Dept Appl Phys & Astron, Sharjah 27272, U Arab Emirates
[6] Aston Univ, Sch Engn & Appl Sci, Mech Engn & Design, Birmingham B4 7ET, W Midlands, England
来源：
JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES | 2022年 / 7卷 / 03期
关键词：
Environmental concerns; Electrochemical energy storage; Metal organic frameworks (MOFs); Synthesis techniques; Post-synthetic modifications; ROOM-TEMPERATURE SYNTHESIS; MICROWAVE SYNTHESIS; STRUCTURAL-CHARACTERIZATION; SOLVOTHERMAL SYNTHESIS; SONOCHEMICAL SYNTHESIS; FACILE SYNTHESIS; ENERGY-STORAGE; SIZE; STABILITY; MIL-101(CR);
D O I：
10.1016/j.jsamd.2022.100465
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Metal-organic frameworks (MOFs) are a versatile category of porous coordination polymers which can be differentiated from other porous nanomaterials due to their fascinating properties such as adaptable surface chemistry, tuneable functionalities, and exceedingly large surface area and uniform/controllable pore size. This newly emerging family of materials with such extraordinary attributes has generated strong research interest, making pristine MOFs and MOF based hybrids a potential platform for a diverse range of applications. However, inferior electrical conductivities and poor chemical stabilities in aqueous solutions have narrowed MOF's application base. In this review article, recent advancement in the synthesis techniques of MOFs and the impact of various production parameters on their physical, chemical, and electrochemical characteristics have been discussed in detail. In addition, their electrochemical performance in rechargeable batteries, supercapacitors, fuel cells and electrochemical sensors has been discussed briefly. Furthermore, future research direction and anticipated challenges have also been reviewed. (C) 2022 Vietnam National University, Hanoi. Published by Elsevier B.V.
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页数：20
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