A facile and green synthesis of MIL-100(Fe) with high-yield and its catalytic performance

被引：69

作者：

Han, Le ^{[1
]}

Qi, Hui ^{[2
]}

Zhang, Dan ^{[1
]}

Ye, Gan ^{[1
]}

Zhou, Wei ^{[3
]}

Hou, Changmin ^{[4
]}

Xu, Wei ^{[4
]}

Sun, Yinyong ^{[1
]}

机构：

[1] Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Heilongjiang, Peoples R China

[2] Jilin Univ, Hosp 2, Changchun 130041, Jilin, Peoples R China

[3] Heilongjiang Univ, Minist Educ, Key Lab Funct Inorgan Mat Chem, Harbin 150080, Heilongjiang, Peoples R China

[4] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 22期

关键词：

METAL-ORGANIC-FRAMEWORK; HETEROGENEOUS CATALYSTS; LEWIS-ACID; ACETALIZATION; MIL-101(CR); ADSORPTION; NANOPARTICLES; SEPARATION; REDUCTION; ADSORBENT;

D O I：

10.1039/c7nj02975f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

MIL-100(Fe) is one of the important metal-organic frameworks due to its fascinating physicochemical properties. Generally, MIL-100(Fe) was synthesized under the conditions of adding HF and solvent. Here, we report that MIL-100(Fe) can be facilely synthesized without the addition of solvent and HF. More importantly, this approach can produce MIL-100(Fe) with a high yield of 93%. Additionally, the obtained MIL-100(Fe) exhibited good catalytic performance in the acetalization of benzaldehyde with methanol. This catalyst can still maintain the initial catalytic activity after five cycles.

引用

页码：13504 / 13509

页数：6