A facile and green synthesis of MIL-100(Fe) with high-yield and its catalytic performance

被引：70

作者：

Han, Le ^{[1
]}

Qi, Hui ^{[2
]}

Zhang, Dan ^{[1
]}

Ye, Gan ^{[1
]}

Zhou, Wei ^{[3
]}

Hou, Changmin ^{[4
]}

Xu, Wei ^{[4
]}

Sun, Yinyong ^{[1
]}

机构：

[1] Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Heilongjiang, Peoples R China

[2] Jilin Univ, Hosp 2, Changchun 130041, Jilin, Peoples R China

[3] Heilongjiang Univ, Minist Educ, Key Lab Funct Inorgan Mat Chem, Harbin 150080, Heilongjiang, Peoples R China

[4] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 22期

关键词：

METAL-ORGANIC-FRAMEWORK; HETEROGENEOUS CATALYSTS; LEWIS-ACID; ACETALIZATION; MIL-101(CR); ADSORPTION; NANOPARTICLES; SEPARATION; REDUCTION; ADSORBENT;

D O I：

10.1039/c7nj02975f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

MIL-100(Fe) is one of the important metal-organic frameworks due to its fascinating physicochemical properties. Generally, MIL-100(Fe) was synthesized under the conditions of adding HF and solvent. Here, we report that MIL-100(Fe) can be facilely synthesized without the addition of solvent and HF. More importantly, this approach can produce MIL-100(Fe) with a high yield of 93%. Additionally, the obtained MIL-100(Fe) exhibited good catalytic performance in the acetalization of benzaldehyde with methanol. This catalyst can still maintain the initial catalytic activity after five cycles.

引用

页码：13504 / 13509

页数：6

共 50 条

[31] Low-Temperature Rapid Synthesis and Performance of the MIL-100(Fe) Monolithic Adsorbent for Dehumidification
Luo, Yanshu
Tan, Bingqiong
Liang, Xianghui
Wang, Shuangfeng
Gao, Xuenong
Zhang, Zhengguo
Fang, Yutang
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2020, 59 (16) : 7291 - 7298
[32] Thermochemical energy applications of green transition metal doped MIL-100(Fe)
Rupam, Tahmid Hasan
Steenhaut, Timothy
Palash, Mujib L.
Filinchuk, Yaroslav
Hermans, Sophie
Saha, Bidyut Baran
CHEMICAL ENGINEERING JOURNAL, 2022, 448
[33] Sandwich-like MIL-100(Fe)@Pt@MIL-100(Fe) nanoparticles for catalytic hydrogenation of 4-nitrophenol
Chen, Zhiming
Xu, Bo
Wang, Xiaomei
Zhang, Li
Yang, Xiaoqing
Li, Cuncheng
CATALYSIS COMMUNICATIONS, 2017, 102 : 17 - 20
[34] Thermochemical energy applications of green transition metal doped MIL-100(Fe)
Rupam, Tahmid Hasan
Steenhaut, Timothy
Palash, Mujib L.
Filinchuk, Yaroslav
Hermans, Sophie
Saha, Bidyut Baran
CHEMICAL ENGINEERING JOURNAL, 2022, 448
[35] Doxorubicin Loading Capacity of MIL-100(Fe): Effect of Synthesis Conditions
Abhik Bhattacharjee
Mihir Kumar Purkait
Sasidhar Gumma
Journal of Inorganic and Organometallic Polymers and Materials, 2020, 30 : 2366 - 2375
[36] Doxorubicin Loading Capacity of MIL-100(Fe): Effect of Synthesis Conditions
Bhattacharjee, Abhik
Purkait, Mihir Kumar
Gumma, Sasidhar
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2020, 30 (07) : 2366 - 2375
[37] Bionanocomposite MIL-100(Fe)/Cellulose as a high-performance adsorbent for the adsorption of methylene blue
Abbasi, Shahla
Nezafat, Zahra
Javanshir, Shahrzad
Aghabarari, Behzad
SCIENTIFIC REPORTS, 2024, 14 (01):
[38] Performance study of heat pump desiccant wheel system based on MIL-100 (Fe) and LiCl@MIL-100(Fe)
Wang, Zepeng
Liu, Zhongbao
Gong, Haohui
Qie, Zhipeng
INTERNATIONAL JOURNAL OF REFRIGERATION, 2025, 171 : 284 - 295
[39] Exploring the catalytic performances of a series of bimetallic MIL-100(Fe-Ni) MOFs
Gimenez-Marques, Monica
Santiago-Portillo, Andrea
Navalon, Sergio
Nouar, Farid
Garcia, Hermenegildo
Serre, Christian
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2018, 74 : E371 - E371
[40] Green synthesis of DOX-loaded hollow MIL-100 (Fe) nanoparticles for anticancer treatment by targeting mitochondria
Zhang, Yechuan
Gu, Zhengxiang
Yun, Seonho
Luo, Kui
Bi, Jingxiu
Jiao, Yan
Zhang, Hu
NANOTECHNOLOGY, 2022, 33 (34)

← 1 2 3 4 5 →