A facile and green synthesis of MIL-100(Fe) with high-yield and its catalytic performance

被引：69
|
作者：
Han, Le [1 ]
Qi, Hui [2 ]
Zhang, Dan [1 ]
Ye, Gan [1 ]
Zhou, Wei [3 ]
Hou, Changmin [4 ]
Xu, Wei [4 ]
Sun, Yinyong [1 ]
机构：
[1] Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Heilongjiang, Peoples R China
[2] Jilin Univ, Hosp 2, Changchun 130041, Jilin, Peoples R China
[3] Heilongjiang Univ, Minist Educ, Key Lab Funct Inorgan Mat Chem, Harbin 150080, Heilongjiang, Peoples R China
[4] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China
来源：
NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 22期
关键词：
METAL-ORGANIC-FRAMEWORK; HETEROGENEOUS CATALYSTS; LEWIS-ACID; ACETALIZATION; MIL-101(CR); ADSORPTION; NANOPARTICLES; SEPARATION; REDUCTION; ADSORBENT;
D O I：
10.1039/c7nj02975f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
MIL-100(Fe) is one of the important metal-organic frameworks due to its fascinating physicochemical properties. Generally, MIL-100(Fe) was synthesized under the conditions of adding HF and solvent. Here, we report that MIL-100(Fe) can be facilely synthesized without the addition of solvent and HF. More importantly, this approach can produce MIL-100(Fe) with a high yield of 93%. Additionally, the obtained MIL-100(Fe) exhibited good catalytic performance in the acetalization of benzaldehyde with methanol. This catalyst can still maintain the initial catalytic activity after five cycles.
引用
收藏
页码：13504 / 13509
页数：6
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