Facile preparation and photophysics of near-infrared luminescent lanthanide(III) monoporphyrinate complexes

被引：102
作者：
Foley, TJ
Harrison, BS
Knefely, AS
Abboud, KA
Reynolds, JR
Schanze, KS [1 ]
Boncella, JM
机构：
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
[2] Univ Florida, Ctr Macromol Sci & Engn, Gainesville, FL 32611 USA
来源：
INORGANIC CHEMISTRY | 2003年 / 42卷 / 16期
关键词：
D O I：
10.1021/ic034217g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis, characterization, and single crystal X-ray diffraction structures of a series of monoporphyrinate, trivalent lanthanide complexes with the monoanionic ligands hydridotris(1-pyrazolyl)borate (Tp) and (cyclopentadienyl)tris(diethylphosphinito)cobaltate (L(OEt)) having the general formulas M(TPP)(L) (M = Yb, Tm, Er, Ho, Nd, Pr; TPP = 5,10,15,20-tetraphenylporphyrinate; L = Tp, L(OEt)) are described. The photophysical properties of these complexes are also presented including their absorption, emission, and transient absorption properties.
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收藏
页码：5023 / 5032
页数：10
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