Transmitting information along oligo-para-phenylenes:: 1,12-stereochemical control in a terphenyl tetracarboxamide

被引：11

作者：

Clayden, Jonathan ^{[1
]}

Vallverdu, Lluis ^{[1
]}

Helliwell, Madeleine ^{[1
]}

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 23期

关键词：

D O I：

10.1039/b701682d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Amide-substituted terphenyls adopt a well-defined conformation that allows the transmission of stereochemical information from a controlling centre to a reaction site 11 bond lengths away, providing a model of how extended polymeric systems might be used to communicate binary information.

引用

页码：2357 / 2359

页数：3

共 28 条

[1] ROLE OF SOLVENT ON THE DIASTEREOSELECTIVITY OF OXAZOLIDINE FORMATION FROM (-)-EPHEDRINE [J].

AGAMI, C ;

RIZK, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (24) :1485-1486

[2] STEREOCHEMISTRY .60. KINETIC CONTROL OF ASYMMETRIC INDUCTION DURING OXAZOLIDINE FORMATION FROM (-)-EPHEDRINE AND AROMATIC-ALDEHYDES [J].

AGAMI, C ;

RIZK, T .

TETRAHEDRON, 1985, 41 (03) :537-540

[3] Barriers to rotation about the chiral axis of tertiary aromatic amides [J].

Ahmed, A ;

Bragg, RA ;

Clayden, J ;

Lai, LW ;

McCarthy, C ;

Pink, JH ;

Westlund, N ;

Yasin, SA .

TETRAHEDRON, 1998, 54 (43) :13277-13294

[4] SEQUENTIAL DIRECTED ORTHO METALATION BORONIC ACID CROSS-COUPLING REACTIONS - A GENERAL REGIOSPECIFIC ROUTE TO OXYGENATED DIBENZO[B,D]PYRAN-6-ONES RELATED TO ELLAGIC ACID [J].

ALO, BI ;

KANDIL, A ;

PATIL, PA ;

SHARP, MJ ;

SIDDIQUI, MA ;

SNIECKUS, V ;

JOSEPHY, PD .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (12) :3763-3768

[5]

[Anonymous], BIOCH SIGNAL TRANSDU

[6]

Balzani V., 2004, MOL DEVICES MACHINES

[7] Conformational preference in aromatic amides bearing chiral ortho substituents:: its origin and application to relayed stereocontrol [J].

Betson, MS ;

Clayden, J ;

Helliwell, M ;

Johnson, P ;

Lai, LW ;

Pink, JH ;

Stimson, CC ;

Vassiliou, N ;

Westlund, N ;

Yasin, SA ;

Youssef, LH .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (03) :424-443

[8] Using dipoles to control the directionality of functional groups:: Syn- and anti-oriented benzene-1,3-dicarboxamides [J].

Betson, MS ;

Clayden, J ;

Lam, HK ;

Helliwell, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (08) :1241-1244

[9] Atroposelectivity in the reactions of ortholithiated aromatic tertiary amides with aldehydes [J].

Bowles, P ;

Clayden, J ;

Helliwell, M ;

McCarthy, C ;

Tomkinson, M ;

Westlund, N .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (17) :2607-2616

[10] Novel concepts in directed biaryl synthesis, part 89 - From dynamic to non-dynamic kinetic resolution of lactone-bridged biaryls: Synthesis of mastigophorene B [J].

Bringmann, G ;

Hinrichs, J ;

Pabst, T ;

Henschel, P ;

Peters, K ;

Peters, EM .

SYNTHESIS-STUTTGART, 2001, (01) :155-167

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