Geostatistical Assessment of the Impact of World War I on the Spatial Occurrence of Soil Heavy Metals

被引:19
作者
Meerschman, Eef [1 ]
Cockx, Liesbet [1 ]
Islam, Mohammad Monirul [1 ]
Meeuws, Fun [1 ]
Van Meirvenne, Marc [1 ]
机构
[1] Univ Ghent, Res Grp Soil Spatial Inventory Tech, Dept Soil Management, Fac Biosci Engn, B-9000 Ghent, Belgium
关键词
Soil heavy metals; World War I; Geostatistics; Spatial variability; COPPER;
D O I
10.1007/s13280-010-0104-6
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Previous research showed a regional Cu enrichment of 6 mg kg(-1) in the top soil of the Ypres war zone (Belgium), caused by corrosion of WWI shell fragments. Further research was required since in addition to Cu, also As, Pb, and Zn were used during the manufacturing of ammunition. Therefore, an additional data collection was conducted in which the initial Cu data set was tripled to 731 data points and extended to eight heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn) which permitted (1) to evaluate the environmental impact of the heavy metals at a regional scale and (2) to assess their regional spatial occurrence by performing an optimized geostatistical modeling. The results showed no pollution at a regional scale, but sometimes locally concentrations exceeded the soil sanitation threshold, especially for Cu, Pb, and Zn. The spatial patterns of Ni and Cr were related to variations in soil texture whereas the occurrences of Cu and Pb were clearly linked to WWI activities. This difference in spatial behavior was confirmed by an analysis of coregionalization.
引用
收藏
页码:417 / 424
页数:8
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