Characterization of polyoxyethylenes according to the number of hydroxy end groups by hydrophilic interaction chromatography at critical conditions for polyethylene glycol

被引：16

作者：

Abrar, Shazia ^{[1
]}

Trathnigg, Bernd ^{[1
]}

机构：

[1] Karl Franzens Univ Graz, Inst Chem, Cent Polymer Lab Mol Characterist CePol MC, A-8010 Graz, Austria

来源：

ANALYTICAL AND BIOANALYTICAL CHEMISTRY | 2011年 / 400卷 / 08期

关键词：

PEG; Ethoxylate; Functionality; Liquid chromatography under critical conditions; HILIC; LIQUID-CHROMATOGRAPHY; POLY(ETHYLENE GLYCOL); ADSORPTION CHROMATOGRAPHY; BLOCK-COPOLYMERS; MACROMOLECULES; POLYMERS; POLY(OXYETHYLENE); SEPARATION; PROTEIN; PHASES;

D O I：

10.1007/s00216-010-4448-3

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

Polyoxyethylenes with different functionality and architecture can be separated according to the number of terminal hydroxy groups on polar stationary phases in acetone water mobile phases containing 90-97% acetone. The best results were obtained on a HILIC column. Typical samples, which can be analyzed by this technique, are polyethylene glycols, their mono- and dialkyl ethers, macromonomers, the fatty esters of PEG, and ethoxylated glycerol.

引用

页码：2531 / 2537

页数：7

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