Two luminescent enantiomorphic 3D metal-organic frameworks with 3D homochiral double helices

被引：56
|
作者：
Zhu, Qilong [1 ,2 ]
Sheng, Tianlu [1 ]
Fu, Ruibiao [1 ]
Tan, Chunhong [1 ,2 ]
Hu, Shengmin [1 ]
Wu, Xintao [1 ]
机构：
[1] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 47期
基金：
美国国家科学基金会;
关键词：
STRUCTURAL-CHARACTERIZATION; COORDINATION POLYMERS; MICROPOROUS FRAMEWORK; ABSOLUTE HELICITY; INDUCTION; CRYSTALLIZATION; COMPLEXES; CHIRALITY; CLUSTER;
D O I：
10.1039/c0cc02550j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two enantiomorphic Cd(II) coordination polymers with three-dimensional homochiral double helices have been assembled respectively from two tripodal enantiopure amino acid derivatives, which exhibit (3,4)-connected (6(3))(6(3).10(3)) topology and strong purple fluorescence.
引用
收藏
页码：9001 / 9003
页数：3
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