Two luminescent enantiomorphic 3D metal-organic frameworks with 3D homochiral double helices

被引：56

作者：

Zhu, Qilong ^{[1
,2
]}

Sheng, Tianlu ^{[1
]}

Fu, Ruibiao ^{[1
]}

Tan, Chunhong ^{[1
,2
]}

Hu, Shengmin ^{[1
]}

Wu, Xintao ^{[1
]}

机构：

[1] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 47期

基金：

美国国家科学基金会;

关键词：

STRUCTURAL-CHARACTERIZATION; COORDINATION POLYMERS; MICROPOROUS FRAMEWORK; ABSOLUTE HELICITY; INDUCTION; CRYSTALLIZATION; COMPLEXES; CHIRALITY; CLUSTER;

D O I：

10.1039/c0cc02550j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two enantiomorphic Cd(II) coordination polymers with three-dimensional homochiral double helices have been assembled respectively from two tripodal enantiopure amino acid derivatives, which exhibit (3,4)-connected (6(3))(6(3).10(3)) topology and strong purple fluorescence.

引用

收藏

页码：9001 / 9003

页数：3

相关论文

共 37 条

[1] Structural characterization of an enantiopure hydroxo-bridged binuclear iron(III) complex with empty one-dimensional helical channels [J].

Alam, MA ;

Nethaji, M ;

Ray, M .

INORGANIC CHEMISTRY, 2005, 44 (05) :1302-1308

[2] Helical and network coordination polymers based on a novel C2-symmetric ligand :: SHG enhancement through specific metal coordination [J].

Anthony, SP ;

Radhakrishnan, TP .

CHEMICAL COMMUNICATIONS, 2004, (09) :1058-1059

[3] Chiral autocatalysis:: where stereochemistry meets the origin of life [J].

Avalos, M ;

Babiano, R ;

Cintas, P ;

Jiménez, JL ;

Palacios, JC .

CHEMICAL COMMUNICATIONS, 2000, (11) :887-892

[4] A homochiral triple helix constructed from an axially chiral bipyridine [J].

Cui, Y ;

Ngo, HL ;

Lin, WB .

CHEMICAL COMMUNICATIONS, 2003, (12) :1388-1389

[5] A luminescent homochiral 3D Cd(II) framework with a threefold interpenetrating uniform net 86 [J].

Feng, Rui ;

Jiang, Fei-Long ;

Chen, Lian ;

Yan, Chun-Feng ;

Wu, Ming-Yan ;

Hong, Mao-Chun .

CHEMICAL COMMUNICATIONS, 2009, (35) :5296-5298

[6] From achiral ligands to chiral coordination polymers: Spontaneous resolution, weak ferromagnetism, and topological ferrimagnetism [J].

Gao, EQ ;

Yue, YF ;

Bai, SQ ;

He, Z ;

Yan, CH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (05) :1419-1429

[7] Copper(II) and cadmium(II) isothiocyanate coordination polymers with 4,4′-bi-1,2,4-triazole [J].

Govor, Evgeniy V. ;

Lysenko, Andrey B. ;

Domasevitch, Konstantin V. ;

Rusanov, Eduard B. ;

Chernega, Alexander N. .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2008, 64 :M117-M120

[8] Chiral porous coordination networks: rational design and applications in enantioselective processes [J].

Kesanli, B ;

Lin, WB .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :305-326

[9] A new Zn(II) coordination polymer with 4-pyridylthioacetate: assemblies of homo-chiral helices with sulfide sites [J].

Kondo, M ;

Miyazawa, M ;

Irie, Y ;

Shinagawa, R ;

Horiba, T ;

Nakamura, A ;

Naito, T ;

Maeda, K ;

Utsuno, S ;

Uchida, F .

CHEMICAL COMMUNICATIONS, 2002, (18) :2156-2157

[10] Synthesis, structural characterization, and interconversion of S-bridged dinuclear and hexanuclear complexes composed of cis(S)-[Co(aet)(2)(en)](+) and trigonal-bipyramidal cadmium(II) (aet equals 2-aminoethanethiolate, en equals ethylenediamine) [J].

Konno, T ;

Okamoto, K .

CHEMISTRY LETTERS, 1996, (11) :975-976

← 1 2 3 4 →