Comparison of metathesis activity of catalysts prepared by anchoring of MoO2(acac)2 on various supports

被引:39
作者
Handzlik, J [1 ]
Ogonowski, J
Stoch, J
Mikolajczyk, M
机构
[1] Cracow Univ Technol, Inst Organ Chem & Technol, Warszawska 24, PL-31155 Krakow, Poland
[2] Polish Acad Sci, Inst Catalysis & Surface Chem, PL-30239 Krakow, Poland
关键词
molybdenum; alumina; silica-alumina; silica; catalyst; tetramethyltin; metathesis;
D O I
10.1007/s10562-005-3751-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The properties and olefin metathesis activity of molybdena - alumina, molybdena - silica - alumina and molybdena - silica catalysts prepared by anchoring of MoO2(acac)(2) complex were compared. The specific activity obtained for molybdena - silica - alumina system is higher than that of molybdena - alumina and molybdena - silica catalysts. This statement concerns also the catalysts treated with tetramethyltin.
引用
收藏
页码:65 / 69
页数:5
相关论文
共 35 条
  • [1] DYNAMIC STUDIES OF THE PHOTOINDUCED METATHESIS OF C3H6 AND PHOTOREDUCTION OF MO WITH CO ON ANCHORED AND IMPREGNATED MO/SIO2 CATALYSTS
    ANPO, M
    KONDO, M
    KUBOKAWA, Y
    LOUIS, C
    CHE, M
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1988, 84 : 2771 - 2782
  • [2] Silica-alumina-supported molybdena catalyst for propene metathesis
    Aritani, H
    Fukuda, O
    Yamamoto, T
    Tanaka, T
    Imamura, S
    [J]. CHEMISTRY LETTERS, 2000, (01) : 66 - 67
  • [3] GRUNERT W, 1991, J PHYS CHEM-US, V95, P1323, DOI 10.1021/j100156a054
  • [4] Anchored and impregnated molybdena-alumina metathesis catalysts - a comparative study
    Handzlik, J
    Ogonowski, J
    Stoch, J
    Mikolajczyk, M
    [J]. APPLIED CATALYSIS A-GENERAL, 2004, 273 (1-2) : 99 - 104
  • [5] Dynamic chemical counting of active centers of molybdena-alumina metathesis catalysts
    Handzlik, J
    Ogonowski, J
    [J]. CATALYSIS LETTERS, 2003, 88 (3-4) : 119 - 122
  • [6] Handzlik J, 2002, PRZEM CHEM, V81, P184
  • [7] Activity of molybdena-alumina metathesis catalysts treated with tetramethyltin
    Handzlik, J
    Ogonowski, J
    [J]. CATALYSIS LETTERS, 2002, 83 (3-4) : 287 - 290
  • [8] HANDZLIK J, 1998, METATEZA OLEFIN ITC, V223
  • [9] STRUCTURE OF MOO3/AL2O3-SIO2 CATALYSTS
    HENKER, M
    WENDLANDT, KP
    VALYON, J
    BORNMANN, P
    [J]. APPLIED CATALYSIS, 1991, 69 (02): : 205 - 220
  • [10] Surface properties and reactivity of Al2O3-supported MoO3 catalysts in ethane oxidative dehydrogenation
    Heracleous, E
    Lee, AF
    Vasalos, IA
    Lemonidou, AA
    [J]. CATALYSIS LETTERS, 2003, 88 (1-2) : 47 - 53