Synthesis and luminescent properties of the novel poly(ethylene-co-acrylic acid) films based on surface modification with lanthanide (Eu3+, Tb3+) complexes

被引：10
作者：
Wu, Yuewen [1 ]
Chu, Yang [1 ]
Yu, Zhenjiang [1 ]
Hao, Haixia [1 ]
Wu, Qingyao [1 ]
Xie, Hongde [1 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
来源：
OPTICAL MATERIALS | 2017年 / 72卷
基金：
新加坡国家研究基金会;
关键词：
Poly(ethylene-co-acrylic acid); Lanthanide complex; Surface modification; Film; Luminescence; RARE-EARTH COMPLEXES; THERMAL-STABILITY; ORGANIC-COMPLEXES; TB(III) COMPLEX; CARBOXYL GROUPS; COPOLYMER; EUROPIUM; LIGANDS; POLYMER; POLYARYLETHERKETONES;
D O I：
10.1016/j.optmat.2017.06.042
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Two kinds of novel fluorescent films have been successfully synthesized by surface modification on the poly(ethylene-co-acrylic acid) films using the lanthanide (Eu3+, Tb3+) complexes. The process consists of three steps: conversion of carboxylic acid groups on the surface of the poly(ethylene-co-acrylic acid) films to acid chloride groups, synthesis of the lanthanide complexes bearing amino groups, and amidation to form the modified films. To characterize the modified films, Fourier transform infrared, thermogravimetric analysis, static water contact angle measurements and photoluminescence tests have been employed. Fourier transform infrared verifies the successful preparation of the lanthanide complexes and the modified poly(ethylene-co-acrylic acid) films. These films can emit strong characteristic red and green light under UV light excitation. In addition, the films both have short lifetime (1.14 ms and 1.21 ms), high thermal stability (T-d = 408 degrees C and 411 degrees C) and, compared with unmodified ones, increased hydrophilicity. All these results suggest that the modified films have potential application as luminescent materials under high temperature. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：436 / 441
页数：6
相关论文
共 41 条
[1]   Synthesis and spectral characterization of lanthanide complexes with 1, 2-diphenyl-4-butyl-3,5-pyrazolidinedione: Luminescent property of Tb(III) complex [J].
Anoop, M. R. ;
Binil, P. S. ;
Suma, S. ;
Sudarsanakumar, M. R. .
JOURNAL OF RARE EARTHS, 2012, 30 (07) :709-715
[2]  
Bing Y, 1998, MONATSHEFTE F R CHEM, V129, P151
[3]   White-Light-Emitting Polymer Composite Film Based on Carbon Dots and Lanthanide Complexes [J].
Chen, Bin ;
Feng, Jiachun .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (14) :7865-7872
[4]   The First Europium( III) b- Diketonate Complex Functionalized Polyhedral Oligomeric Silsesquioxane [J].
Chen, Xiaofan ;
Zhang, Panning ;
Wang, Tianren ;
Li, Huanrong .
CHEMISTRY-A EUROPEAN JOURNAL, 2014, 20 (09) :2551-2556
[5]   Preparation of lanthanide (Eu3+, Tb3+)-complex-grafted copolymer of methyl methacrylate and maleic anhydride films and the promising application as LED luminous layers [J].
Chu, Yang ;
Hao, Haixia ;
Xie, Hongde ;
Chen, Cuili ;
Cai, Peiqing ;
Seo, Hyo Jin .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (07) :5615-5622
[6]   Hybrid materials based on lanthanide organic complexes: a review [J].
Feng, Jing ;
Zhang, Hongjie .
CHEMICAL SOCIETY REVIEWS, 2013, 42 (01) :387-410
[7]   Films Made from Poly(vinyl alcohol-co-ethylene) and Soluble Biopolymers Isolated from Municipal Biowaste [J].
Franzoso, Flavia ;
Tabasso, Silvia ;
Antonioli, Diego ;
Montoneri, Enzo ;
Persico, Paola ;
Laus, Michele ;
Mendichi, Raniero ;
Negre, Michele .
JOURNAL OF APPLIED POLYMER SCIENCE, 2015, 132 (04)
[8]   Polymer surface modification for the attachment of bioactive compounds [J].
Goddard, J. M. ;
Hotchkiss, J. H. .
PROGRESS IN POLYMER SCIENCE, 2007, 32 (07) :698-725
[9]   Coordination bonding construction, characterization and photoluminescence of ternary lanthanide (Eu3+, Tb3+) hybrids with phenylphenacyl-sulfoxide modified bridge and polymer units [J].
Guo, Lei ;
Yan, Bing ;
Liu, Jin-Liang ;
Sheng, Kai ;
Wang, Xiao-Long .
DALTON TRANSACTIONS, 2011, 40 (03) :632-638
[10]  
Jenkins W.A. e., 1991, Packaging Foods with Plastics
12345