FeSO4•7H2O-catalyzed four-component synthesis of protected homoallylic amines

被引：42
|
作者：
Song, Qi-Yi [1 ]
Yang, Bai-Ling [1 ]
Tian, Shi-Kai [1 ]
机构：
[1] Univ Sci & Technol China, Sch Chem & Mat Sci, Dept Chem, Hefei 230026, Anhui, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 14期
关键词：
D O I：
10.1021/jo0704558
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient catalytic four-component reaction of carbonyl compounds (or acetals/ketals), benzyl chloroformate (CbzCl), 1,1,1,3,3,3-hexamethyldisilazane (HMDS), and allyltrimethylsilane has been successfully developed to produce Cbz-protected homoallylic amines in the presence of 5 mol % of iron(II) sulfate heptahydrate (FeSO4 center dot 7H(2)O), an inexpensive and environmentally friendly catalyst, at room temperature.
引用
收藏
页码：5407 / 5410
页数：4
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