Inner-shell excitation of ethanol cluster at OK-edge

被引：11

作者：

Tamenori, Y

Yamaguchi, T

Okada, K

Tabayashi, K

Gejo, T

Honma, K

机构：

[1] JASRI, Spring 8, Mikazuki 6795198, Japan

[2] Univ Hyogo, Dept Mat Sci, Kamigori 6781297, Japan

[3] Hiroshima Univ, Dept Chem, Higashihiroshima 7398526, Japan

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 2005年 / 144卷

关键词：

ethanol cluster; hydrogen-bonding; soft x-ray;

D O I：

10.1016/j.elspec.2005.01.147

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Inner-shell excitation of ethanol cluster was investigated using a partial-ion-yield method at the oxygen K-edge. The resonance feature corresponding to the excitation to the 3sa' unoccupied orbital was not observed in the partial yield spectra of cluster ions, while it is clearly seen in the total ion yield spectrum. The absence of this feature is explained by the changes in local electronic structures owing to the hydrogen bonding in the clusters. (c) 2005 Elsevier B.V. All rights reserved.

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页码：235 / 238

页数：4

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