The gem-dialkyl effect in electron transfer reactions:: Rapid synthesis of seven-membered rings through an electrochemical annulation

被引：42

作者：

Sperry, JB ^{[1
]}

Wright, DL ^{[1
]}

机构：

[1] Dartmouth Coll, Dept Chem, Hanover, NH 03755 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 22期

关键词：

D O I：

10.1021/ja051826+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An electrochemical furan annulation strategy has been developed for the synthesis of seven-membered rings. Key to the success of the annulation is the placement of a gem-dialkyl group in the tether. Voltammetric studies indicate that this effect lowers the oxidation potential by approximately 110 mV. Copyright © 2005 American Chemical Society.

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页码：8034 / 8035

页数：2

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