Water-Soluble and Biocompatible Cyclometalated Iridium(III) Complexes: Synthesis, Luminescence and Sensing Application

被引:32
|
作者
Li, Mei-Jin [1 ]
Jiao, Pengchong [1 ]
He, Weiwen [1 ]
Yi, Changqing [2 ]
Li, Cheuk-Wing [2 ,3 ]
Chen, Xi [1 ]
Chen, Guo-Nan [1 ]
Yang, Mengsu [2 ]
机构
[1] Fuzhou Univ, Key Lab Anal & Detect Technol Food Safety, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Minist Educ,Dept Chem, Fuzhou 350108, Peoples R China
[2] City Univ Hong Kong, Dept Biol & Chem, Hong Kong, Hong Kong, Peoples R China
[3] S China Univ Technol, Sch Mat Sci & Engn, Natl Engn Res Ctr Tissue Restorat & Reconstruct, Guangzhou 510640, Peoples R China
关键词
Iridium; Luminescence; Biosensors; Water-soluble complexes; Lectin; ELECTROGENERATED CHEMILUMINESCENCE; DINUCLEAR IRIDIUM(III); ABSORPTION-SPECTRA; METAL-COMPLEXES; CELLULAR UPTAKE; RUTHENIUM; ELECTROCHEMILUMINESCENCE; MONONUCLEAR;
D O I
10.1002/ejic.201000991
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two new iridium(III) complexes with good water-solubility and biocompatibility have been synthesized and characterized. These two iridium(III) complexes showed strong luminescence with high quantum efficiency. Preliminary experiments demonstrated the feasibility of sensing lectin by formation of iridium(III) complexes. These new iridium(III) complexes might open up new applications in biosensor and chemosensor.
引用
收藏
页码:197 / 200
页数:4
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