Water-Soluble and Biocompatible Cyclometalated Iridium(III) Complexes: Synthesis, Luminescence and Sensing Application

被引:33
作者
Li, Mei-Jin [1 ]
Jiao, Pengchong [1 ]
He, Weiwen [1 ]
Yi, Changqing [2 ]
Li, Cheuk-Wing [2 ,3 ]
Chen, Xi [1 ]
Chen, Guo-Nan [1 ]
Yang, Mengsu [2 ]
机构
[1] Fuzhou Univ, Key Lab Anal & Detect Technol Food Safety, Fujian Prov Key Lab Anal & Detect Technol Food Sa, Minist Educ,Dept Chem, Fuzhou 350108, Peoples R China
[2] City Univ Hong Kong, Dept Biol & Chem, Hong Kong, Hong Kong, Peoples R China
[3] S China Univ Technol, Sch Mat Sci & Engn, Natl Engn Res Ctr Tissue Restorat & Reconstruct, Guangzhou 510640, Peoples R China
关键词
Iridium; Luminescence; Biosensors; Water-soluble complexes; Lectin; ELECTROGENERATED CHEMILUMINESCENCE; DINUCLEAR IRIDIUM(III); ABSORPTION-SPECTRA; METAL-COMPLEXES; CELLULAR UPTAKE; RUTHENIUM; ELECTROCHEMILUMINESCENCE; MONONUCLEAR;
D O I
10.1002/ejic.201000991
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two new iridium(III) complexes with good water-solubility and biocompatibility have been synthesized and characterized. These two iridium(III) complexes showed strong luminescence with high quantum efficiency. Preliminary experiments demonstrated the feasibility of sensing lectin by formation of iridium(III) complexes. These new iridium(III) complexes might open up new applications in biosensor and chemosensor.
引用
收藏
页码:197 / 200
页数:4
相关论文
共 43 条
  • [1] Chemical glycobiology
    Bertozzi, CR
    Kiessling, LL
    [J]. SCIENCE, 2001, 291 (5512) : 2357 - 2364
  • [2] Green electrochemiluminescence from ortho-metalated tris(2-phenylpyridine)iridium(III)
    Bruce, D
    Richter, MM
    [J]. ANALYTICAL CHEMISTRY, 2002, 74 (06) : 1340 - 1342
  • [3] ABSORPTION-SPECTRA, LUMINESCENCE PROPERTIES, AND ELECTROCHEMICAL-BEHAVIOR OF CYCLOMETALATED IRIDIUM(III) AND RHODIUM(III) COMPLEXES WITH A BIS(PYRIDYL)TRIAZOLE LIGAND
    CALOGERO, G
    GIUFFRIDA, G
    SERRONI, S
    RICEVUTO, V
    CAMPAGNA, S
    [J]. INORGANIC CHEMISTRY, 1995, 34 (03) : 541 - 545
  • [4] CARMICHAEL J, 1987, CANCER RES, V47, P936
  • [5] Chen HL, 2007, HEPATOLOGY, V46, p720A
  • [6] Highly sensitive biological and chemical sensors based on reversible fluorescence quenching in a conjugated polymer
    Chen, LH
    McBranch, DW
    Wang, HL
    Helgeson, R
    Wudl, F
    Whitten, DG
    [J]. PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1999, 96 (22) : 12287 - 12292
  • [7] Photophysical and photochemical properties of pyranine/methyl viologen complexes in solution and in supramolecular aggregates: A switchable complex
    de Borba, EB
    Amaral, CLC
    Politi, MJ
    Villalobos, R
    Baptista, MS
    [J]. LANGMUIR, 2000, 16 (14) : 5900 - 5907
  • [8] Luminescent mononuclear and dinuclear iridium(III) cyclometalated complexes immobilized in a polymeric matrix as solid-state oxygen sensors
    Di Marco, G
    Lanza, M
    Mamo, A
    Stefio, I
    Di Pietro, C
    Romeo, G
    Campagna, S
    [J]. ANALYTICAL CHEMISTRY, 1998, 70 (23) : 5019 - 5023
  • [9] Saccharide detection based on the amplified fluorescence quenching of a water-soluble poly(phenylene ethynylene) by a boronic acid functionalized benzyl viologen derivative
    DiCesare, N
    Pinto, MR
    Schanze, KS
    Lakowicz, JR
    [J]. LANGMUIR, 2002, 18 (21) : 7785 - 7787
  • [10] Water-soluble conjugated oligomers: Effect of chain length and aggregation on photoluminescence-quenching efficiencies
    Gaylord, BS
    Wang, SJ
    Heeger, AJ
    Bazan, GC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (26) : 6417 - 6418