Activated carbon supported cobalt catalysts for advanced oxidation of organic contaminants in aqueous solution

被引：397
作者：
Shukla, Pradeep R.
Wang, Shaobin [1 ]
Sun, Hongqi
Ang, H. Ming
Tade, Moses
机构：
[1] Curtin Univ Technol, Dept Chem Engn, Perth, WA 6845, Australia
来源：
APPLIED CATALYSIS B-ENVIRONMENTAL | 2010年 / 100卷 / 3-4期
关键词：
Activated carbon; Cobalt; Phenol; Advanced oxidation process; Water treatment; HETEROGENEOUS ACTIVATION; WASTE-WATER; DEGRADATION; FENTON; PEROXYMONOSULFATE; KINETICS; OXIDE; ACID; DYES;
D O I：
10.1016/j.apcatb.2010.09.006
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A heterogeneous cobalt catalyst was prepared by impregnation of cobalt ion on an activated carbon (AC) and used to activate peroxymonosulphate (PMS) for advanced oxidation of phenol in aqueous solution The Co/AC catalyst was characterised by several techniques such as XRD EDS SEM and TGA It was found that Co2O3 was the major form of Co species and was homogeneously distributed on the activated carbon sui face Co/AC exhibited high activity in oxidation of phenol with sulphate radicals and 100% decomposition and 80% TOC removal could be achieved in 60 min at the conditions of 500 ml phenol solution of 25 ppm 0 1 g catalyst and 1 g peroxymonosulphate The catalyst also exhibited stable performance after several rounds of regeneration Several operational parameters such as catalyst and oxidant amount temperature on the rate of oxidation were found to influence the phenol oxidation (C) 2010 Elsevier B V All rights reserved
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页码：529 / 534
页数：6
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