Pd(II)-catalyzed intermolecular 1,2-diamination of conjugated dienes

被引：258
作者：
Bar, GLJ [1 ]
Lloyd-Jones, GC [1 ]
Booker-Milburn, KI [1 ]
机构：
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 20期
关键词：
D O I：
10.1021/ja051181d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Pd(II) chloride precatalyst, in the presence of 1 equiv of benzoquinone, effects highly efficient, regioselective 1,2-diamination of 1,3-dienes using dialkyl ureas under mild conditions. There is no requirement for a large excess of diene. Copyright © 2005 American Chemical Society.
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页码：7308 / 7309
页数：2
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