Theoretical studies of preparation of core-shell nanoparticles by electrochemical metal deposition

被引:14
|
作者
Oviedo, O. A. [1 ]
Mariscal, M. M. [1 ]
Leiva, E. P. M. [1 ]
机构
[1] Univ Nacl Cordoba, INFIQC, Dept Matemat & Fis, Fac Ciencias Quim, RA-5000 Cordoba, Argentina
关键词
Nanoparticle; Underpotential deposition; Core-shell; Size effect; Nanotechnology; SEED-MEDIATED GROWTH; WET CHEMICAL SYNTHESIS; GOLD NANOPARTICLES; COLLOIDAL GOLD; NANORODS; SIZE; THERMODYNAMICS; NUCLEATION; DEPENDENCE; MONOLAYER;
D O I
10.1016/j.electacta.2010.03.059
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In the present work we discuss the statistical mechanical framework for predicting the decoration of metallic nanoparticles using electrochemical methods in thermodynamic equilibrium It is found that depending on the interactions between the two metals controlled decoration may be achieved for core-shell nanoparticles in undersaturation and oversaturation conditions The concept of underpotential deposition is discussed for the case of nanoparticles with the finding that this phenomenon may be size dependent (C) 2010 Elsevier Ltd All rights reserved
引用
收藏
页码:8244 / 8251
页数:8
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