Structural characterization of a novel self-assembly heterohexanuclear complex:: [Ni2Ag4(μ-dppm)4(pymt)6](SbF6)2 • 2DMF • H2O

被引：5
|
作者：
Xu, Hong-wu [1 ]
Pin, Lin
Li, Jin-xia
Chen, Zhong-ning
Wu, Ji-gui
机构：
[1] ZhongYuan Univ Technol, Dept Chem & Mat Engn, Zhengzhou 450007, Henan, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian 350002, Peoples R China
[3] Lanzhou Univ, Dept Chem, Lanzhou 73000, Gansu, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 2007年 / 32卷 / 06期
关键词：
D O I：
10.1007/s11243-007-0251-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel heterohexanuclear complex [Ni2Ag4(mu-dppm)(4)(pymt)(6)](SbF (6))(2) center dot 2DMF center dot H2O (1), was synthesized by self-assembly with [Ag-2(mu-dppm)(2)(MeCN)(2)](SbF6) (2) and [Et4N][Ni(pymt)(3)] (dppm = bis(diphenylphosphino)methane, pymt = pyrimidine-2-thiolate) as components and characterized by IR spectra, elemental analysis, (1) H-NMR spectrum, P-31-NMR spectrum and Visible-Ultraviolet spectrum. Structure of the complex was determined by X-ray analysis.
引用
收藏
页码：781 / 783
页数：3
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