Structural characterization of a novel self-assembly heterohexanuclear complex:: [Ni2Ag4(μ-dppm)4(pymt)6](SbF6)2 • 2DMF • H2O

被引：5
|
作者：
Xu, Hong-wu [1 ]
Pin, Lin
Li, Jin-xia
Chen, Zhong-ning
Wu, Ji-gui
机构：
[1] ZhongYuan Univ Technol, Dept Chem & Mat Engn, Zhengzhou 450007, Henan, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian 350002, Peoples R China
[3] Lanzhou Univ, Dept Chem, Lanzhou 73000, Gansu, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 2007年 / 32卷 / 06期
关键词：
D O I：
10.1007/s11243-007-0251-1
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel heterohexanuclear complex [Ni2Ag4(mu-dppm)(4)(pymt)(6)](SbF (6))(2) center dot 2DMF center dot H2O (1), was synthesized by self-assembly with [Ag-2(mu-dppm)(2)(MeCN)(2)](SbF6) (2) and [Et4N][Ni(pymt)(3)] (dppm = bis(diphenylphosphino)methane, pymt = pyrimidine-2-thiolate) as components and characterized by IR spectra, elemental analysis, (1) H-NMR spectrum, P-31-NMR spectrum and Visible-Ultraviolet spectrum. Structure of the complex was determined by X-ray analysis.
引用
收藏
页码：781 / 783
页数：3
相关论文
共 50 条
  • [1] Structural characterization of a novel self-assembly heterohexanuclear complex: [Ni2Ag4(μ-dppm)4(pymt)6](SbF6)2 · 2DMF · H2O
    Hong-wu Xu
    Lin Pin
    Jin-xia Li
    Zhong-ning Chen
    Ji-gui Wu
    Transition Metal Chemistry, 2007, 32 : 781 - 783
  • [2] Self-assembly luminescent complexes with [Ag2 (μ-dppm)2 (MeCN)2](SbF6)2 and tptz as components
    Xu, Hong-wu
    Li, Jin-xia
    Pin, Lin
    Chen, Zhong-ning
    Wu, Ji-gui
    TRANSITION METAL CHEMISTRY, 2007, 32 (06) : 839 - 844
  • [3] Self-assembly luminescent complexes with [Ag2 (μ-dppm)2 (MeCN)2](SbF6)2 and tptz as components
    Hong-wu Xu
    Jin-xia Li
    Lin Pin
    Zhong-ning Chen
    Ji-gui Wu
    Transition Metal Chemistry, 2007, 32 : 839 - 844
  • [4] The Platinum(II) Salt Pt(H2O)4(SbF6)2
    Seppelt, Konrad
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2010, 636 (13-14): : 2391 - 2393
  • [5] Synthesis,CrystalStructureandLuminescencePropertyof[Ag2（dppm）2（NMP）2]（SbF6）2·4H2O·3CH2Cl2
    WEI YongQin WU KeChen ZHUANG BoTao ZHOU ZhangFeng State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter The Chinese Academy of Sciences Fuzhou Fujian China
    结构化学, 2005, (12) : 1363 - 1368+1349
  • [6] Synthesis, Crystal Structure and Luminescence Property of [Ag2（dppm）2（NMP）2]（SbF6）2·4H2O·3CH2Cl2
    WEI Yong-Qin WU Ke-Chen② ZHUANG Bo-Tao ZHOU Zhang-Feng (State Key Laboratory of Structural Chemistry
    Chinese Journal of Structural Chemistry, 2005, (12) : 1363 - 1368
  • [7] Synthesis, crystal structure and luminescence property of [Ag2(dppm)2(NMP)2](SbF6)2•4H2O•3CH2Cl2
    Wei, YQ
    Wu, KC
    Zhuang, BT
    Zhou, ZF
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (12) : 1363 - 1368
  • [8] Self-assembly and crystal structures of two heteronuclear complexes with [Ag2(μ-dppm)2(MeCN)2](SbF6)2 and [Bu4N]2[M(mnt)3] (M=Mo, W) as components
    Hong-wu Xu
    Ji-gui Wu
    Zhong-ning Chen
    Transition Metal Chemistry, 2008, 33 : 17 - 21
  • [9] Self-assembly and crystal structures of two heteronuclear complexes with [Ag2(μ-dppm)2(MeCN)2](SbF6)2 and [Bu4N]2[M(mnt)3] (M=Mo, W) as components
    Xu, Hong-wu
    Wu, Ji-gui
    Chen, Zhong-ning
    TRANSITION METAL CHEMISTRY, 2008, 33 (01) : 17 - 21
  • [10] Synthesis and Structural Characterization of a Ni（Ⅱ） Complex [Ni（H2O）4（4,4'-bipy）2]（hca）2
    ZHOU Qiu-Xuana XU Qing-Fenga LU Jian-Meia
    结构化学, 2006, (11) : 1392 - 1396
12345