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A novel fibre-coated sorbent for rapid removal of heavy metals from wastewater. Sorption of Zinc(II) from dilute aqueous solutions in the presence of high concentrations of common salts
被引:0
|作者:
Chanda, M
[1
]
Pillay, SA
[1
]
机构:
[1] Indian Inst Sci, Dept Chem Engn, Bangalore 560012, Karnataka, India
关键词:
acrylic fibre;
zinc ion;
ion-exchange resin;
poly acrylonitrile;
polyethylenimine;
sorbent;
sorption;
D O I:
暂无
中图分类号:
O69 [应用化学];
学科分类号:
081704 ;
摘要:
The commercial acrylic fibre "Cashmilon" was partially hydrolyzed to convert a fraction of its nitrile (-CN) groups to carboxylic acid (-COOH) groups and then coated with polyethylenimine (PEI) resin and cross-linked with glutaraldehyde to produce a novel gel-coated fibrous sorbent with multiple functionalities of cationic, anionic and chelating types, and significantly faster sorption kinetics than bead-form sorbents. The sorption properties of the fibrous sorbent were measured using Zn(II) in aqueous solution as the sorbate to determine the effects of pH and the presence of common ions in the solution on the sorption capacity. The rate of sorption on the gel-coated fibre was measured in comparison with that on Amberlite IRA-68 weak-base resin beads, to demonstrate the marked difference between fibre and bead-form sorbents in their kinetic behaviour.
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页码:156 / 163
页数:8
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