Dimethoxymethane Production via Catalytic Hydrogenation of Carbon Monoxide in Methanol Media

被引：17
作者：
Ahmad, Waqar [1 ]
Chan, Fan Liang [1 ]
Chaffee, Alan L. [2 ]
Wang, Huanting [1 ]
Hoadley, Andrew [1 ]
Tanksale, Akshat [1 ]
机构：
[1] Monash Univ, Dept Chem Engn, Clayton, Vic 3800, Australia
[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2020年 / 8卷 / 04期
基金：
澳大利亚研究理事会;
关键词：
Syngas hydrogenation; Dimethoxymethane; Formaldehyde; Heterogeneous catalysis; Zeolite; HIERARCHICAL BETA-ZEOLITE; DIMETHYL ETHERS; NI-RU; FORMALDEHYDE; CU; NANOPARTICLES; REDUCTION; ALUMINA; BIOMASS; TPR;
D O I：
10.1021/acssuschemeng.9b06913
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dimethoxymethane (OME1) is an important chemical and has vast applications. However, the current commercial method to produce this chemical suffers high exergy loss. In this study, we demonstrate a one-pot approach to synthesize OME1 from syngas. OME1 was produced using a Ru promoted catalyst via a cascade reaction of hydrogenation of carbon monoxide into formaldehyde, followed by acetalization with methanol in liquid media. Results show that the catalytic activity of these Ru promoted catalysts in converting CO and H-2 to OME1 was in the following order: Ru-Ni > Ru-Cu > Ru.
引用
收藏
页码：2081 / 2092
页数：23
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