Structure of oxychloride glasses by neutron and x-ray 'difference' and x-ray photoelectron spectroscopy

被引：2
作者：
Johnson, JA
Holland, D
Urquidi, J
Gee, IA
Benmore, CJ
Johnson, CE
机构：
[1] Argonne Natl Lab, Div Energy Technol, Argonne, IL 60439 USA
[2] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England
[3] Argonne Natl Lab, Intense Pulsed Neutron Source, Argonne, IL 60439 USA
[4] No Illinois Univ, Dept Phys, De Kalb, IL 60115 USA
来源：
JOURNAL OF PHYSICS-CONDENSED MATTER | 2003年 / 15卷 / 27期
关键词：
D O I：
10.1088/0953-8984/15/27/303
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
A previous study of the binary system, [Sb2O3](x)-[ZnCl2](1-x) (Johnson et al 2003 J. Phys.: Condens. Matter 15 755-64), where nominally x = 0.25, 0.50, 0.75 and 1.00, has been extended to include Sb2O3-PbCl2. Information about the structure has been obtained from a combination of neutron and x-ray diffraction measurements, which were complemented by x-ray photoelectron spectroscopy. The data clearly show preferential bonding of oxygen to antimony and chlorine to zinc or lead in a single-phase glass with minimal change in the polyhedral structure with composition. The structure appears to be controlled by the need to avoid Sb-Cl-Sb links.
引用
收藏
页码：4679 / 4693
页数：15
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