Going against the flow: Os(II)-to-Ru(II) energy transfer in rod-like polypyridyl chromophore

被引：7
|
作者：
Laramee-Milette, Baptiste [1 ]
Hanan, Garry S. [1 ]
机构：
[1] Univ Montreal, Dept Chim, 5155 Ch Rampe,Pavillon JA Bombardier, Montreal, PQ H3T 2B1, Canada
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 76期
关键词：
ELECTRON-TRANSFER PROCESSES; TERPYRIDINE-TYPE COMPLEXES; METAL-COMPLEXES; LUMINESCENCE PROPERTIES; ELECTROCHEMICAL-BEHAVIOR; DINUCLEAR COMPLEXES; ABSORPTION-SPECTRA; BRIDGING LIGANDS; PHOTOINDUCED PROCESSES; INTERCOMPONENT ENERGY;
D O I：
10.1039/c7cc03541a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The judicious design of a unique mixed-metal Ru-Os molecular rod led to the first photoinduced energy transfer from osmium-toruthenium in a polypyridyl complex. The absorbed light is directed from the osmium metal center to the peripheral ruthenium moieties, where only the low energy luminescence from the heteroleptic ruthenium phen-hpp complex was observed.
引用
收藏
页码：10496 / 10499
页数：4
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