RETRACTED: One-pot synthesis of O-doped BN nanosheets as a capacitive deionization electrode for efficient removal of heavy metal ions from water (Publication with Expression of Concern. See vol. 7, pg. 2919, 2019) (Retracted article. See vol. 7, pg. 20445, 2019)

被引:30
作者
Chen, Ming Ming [1 ,2 ]
Wei, Da [1 ,2 ]
Chu, Wei [3 ]
Wang, Tao [1 ,2 ]
Tong, Dong Ge [1 ,2 ]
机构
[1] Chengdu Univ Technol, State Key Lab Geohazard Prevent & Geoenvironm, Chengdu 610059, Sichuan, Peoples R China
[2] Chengdu Univ Technol, Coll Mat & Chem & Chem Engn, Collaborat Innovat Ctr Panxi Strateg Mineral Res, Chengdu 610059, Peoples R China
[3] Sichuan Univ, Inst New Energy & Low Carbon Technol, Sch Chem Engn, Chengdu 610065, Sichuan, Peoples R China
关键词
ACTIVATED CARBON ELECTRODES; BORON-NITRIDE NANOSHEETS; SOLID-STATE NMR; AQUEOUS-SOLUTIONS; WASTE-WATER; MAS NMR; HYDROUS HYDRAZINE; COPPER IONS; GRAPHENE; ADSORPTION;
D O I
10.1039/c7ta05459a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
O-Doped BN nanosheets with a thickness of 1.033 nm were prepared via the direct reaction of CuB23 with NOCl at room temperature in ionic liquids. It had a large high specific surface area of 858 m(2) g(-1), and showed a high electrical conductivity of 34.3 S m(-1) and a good specific capacity of 187 F g(-1). Meanwhile, the obtained sample demonstrated excellent performance as the electrode material for capacitive deionization (CDI) to remove Cd2+ from water in a wide range of concentrations from 0.05 to 600 ppm with a maximum adsorption capacity of 2281 mg g(-1). It is attributed to its unique structural characteristics and the ability of its NO-groups to coordinate Cd2+ which promotes the electrosorption. More importantly, it exhibited outstanding capability for the total, rapid, and simultaneous removal of multiple metal ions (Zn2+, Cd2+, Pb2+, Ni2+, Co2+, Cu2+, Mg2+, Ca2+, Fe2+, Fe3+ and Na+) by CDI within 20 min. These results suggest promising applications of our BNO nanosheets for water purification and water-softening devices based on CDI.
引用
收藏
页码:17029 / 17039
页数:11
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