Synthesis and Properties of 1,3-Dithiole[4]dendralenes, in Which Two Thiophene Rings Are Inserted

被引：10

作者：

Nishiwaki, Masataka ^{[1
,2
]}

Tezuka, Mami ^{[1
]}

Shirahata, Takashi ^{[1
,2
]}

Misaki, Yohji ^{[1
,2
]}

机构：

[1] Ehime Univ, Grad Sch Sci & Engn, Dept Appl Chem, Matsuyama, Ehime 7908577, Japan

[2] JST, Res Seeds Program, Matsuyama, Ehime 7908577, Japan

来源：

CHEMISTRY LETTERS | 2011年 / 40卷 / 05期

基金：

日本学术振兴会;

关键词：

TTF; SYSTEMS;

D O I：

10.1246/cl.2011.467

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel 1,3-dithiole[4]dendralene derivatives 3 with two thiophene spacers were synthesized. Cyclic voltammetry and spectroelectrochemistry suggested the dications of most derivatives of 3 have dimeric thiophene quinoid radical cation structures, while tetramethyltetrakis(methoxycarbonyl) derivative 3Bd adopts a vinylogous TTF dication structure.

引用

页码：467 / 469

页数：3

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