Electron paramagnetic resonance of γ-irradiated glycyl-L-glutamine monohydrate, iminodiacetic acid and methyliminodiacetic acid

被引：16

作者：

Aydin, M. ^{[1
]}

Osmanoglu, Y. E. ^{[2
]}

Baskan, M. H. ^{[2
]}

机构：

[1] Adiyaman Univ, Fac Educ, TR-02100 Adiyaman, Turkey

[2] Dicle Univ, Fac Arts & Sci, Dept Phys, TR-21280 Diyarbakir, Turkey

来源：

RADIATION EFFECTS AND DEFECTS IN SOLIDS | 2008年 / 163卷 / 01期

关键词：

EPR; free radicals; gamma irradiation; amino acid; iminodiacetic acid derivatives;

D O I：

10.1080/10420150701464343

中图分类号：

TL [原子能技术]; O571 [原子核物理学];

学科分类号：

0827 ; 082701 ;

摘要：

The electron paramagnetic resonances of gamma-irradiated powders of glycyl- L- glutamine monohydrate, iminodiacetic acid and methyliminodiacetic acid were investigated at room temperature. The observed species in glycyl- L- glutamine monohydrate powders were attributed to the CH2<(C)over dot>NHCOOH radical; and those in iminodiacetic acid and methyliminodiacetic acid powders to the HN<(C)over dot>HCH2(COOH)(2) and H3CN<(C)over dot>HCH2(COOH)(2) radicals respectively. The spectra were computer simulated and the g values of the radicals and the hyperfine structure constants of the unpaired electron with nearby protons and N-14 nucleus were determined. The results were found to be in good agreement with the existing literature data.

引用

页码：47 / 53

页数：7

共 23 条

[1] EPR of gamma irradiated Nα-monochloroacetyl-α-aminoisobutyric acid [J].