Reactivity of a Phosphaalkyne with Pentaarylboroles

被引：38

作者：

Barnard, Jonathan H. ^{[1
]}

Yruegas, Sam ^{[1
]}

Couchman, Shannon A. ^{[2
]}

Wilson, David J. D. ^{[2
]}

Dutton, Jason L. ^{[2
]}

Martin, Caleb D. ^{[1
]}

机构：

[1] Baylor Univ, Dept Chem & Biochem, One Bear Pl 97348, Waco, TX 76798 USA

[2] La Trobe Univ, La Trobe Inst Mol Sci, Dept Chem & Phys, Melbourne, Vic 3086, Australia

来源：

ORGANOMETALLICS | 2016年 / 35卷 / 07期

关键词：

RING EXPANSION; FREE BOROLES; PENTAPHENYLBOROLE; ANTIAROMATICITY; COORDINATION; HETEROCYCLES; PHOSPHINES; ACTIVATION; SYSTEM; AZIDES;

D O I：

10.1021/acs.organomet.6b00123

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of pentaarylboroles with 1-adamantylphosphaalkyne led to the formation of unique 1-phospha-6-boratricyclo-hept-3enes. A rational mechanism for this transformation is proposed and supported by DFT calculations.

引用

页码：929 / 931

页数：3

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