Reactivity of a Phosphaalkyne with Pentaarylboroles

被引：37
作者：
Barnard, Jonathan H. [1 ]
Yruegas, Sam [1 ]
Couchman, Shannon A. [2 ]
Wilson, David J. D. [2 ]
Dutton, Jason L. [2 ]
Martin, Caleb D. [1 ]
机构：
[1] Baylor Univ, Dept Chem & Biochem, One Bear Pl 97348, Waco, TX 76798 USA
[2] La Trobe Univ, La Trobe Inst Mol Sci, Dept Chem & Phys, Melbourne, Vic 3086, Australia
来源：
ORGANOMETALLICS | 2016年 / 35卷 / 07期
关键词：
RING EXPANSION; FREE BOROLES; PENTAPHENYLBOROLE; ANTIAROMATICITY; COORDINATION; HETEROCYCLES; PHOSPHINES; ACTIVATION; SYSTEM; AZIDES;
D O I：
10.1021/acs.organomet.6b00123
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of pentaarylboroles with 1-adamantylphosphaalkyne led to the formation of unique 1-phospha-6-boratricyclo-hept-3enes. A rational mechanism for this transformation is proposed and supported by DFT calculations.
引用
收藏
页码：929 / 931
页数：3
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