Reactivity of a Phosphaalkyne with Pentaarylboroles

被引:37
作者
Barnard, Jonathan H. [1 ]
Yruegas, Sam [1 ]
Couchman, Shannon A. [2 ]
Wilson, David J. D. [2 ]
Dutton, Jason L. [2 ]
Martin, Caleb D. [1 ]
机构
[1] Baylor Univ, Dept Chem & Biochem, One Bear Pl 97348, Waco, TX 76798 USA
[2] La Trobe Univ, La Trobe Inst Mol Sci, Dept Chem & Phys, Melbourne, Vic 3086, Australia
关键词
RING EXPANSION; FREE BOROLES; PENTAPHENYLBOROLE; ANTIAROMATICITY; COORDINATION; HETEROCYCLES; PHOSPHINES; ACTIVATION; SYSTEM; AZIDES;
D O I
10.1021/acs.organomet.6b00123
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reactions of pentaarylboroles with 1-adamantylphosphaalkyne led to the formation of unique 1-phospha-6-boratricyclo-hept-3enes. A rational mechanism for this transformation is proposed and supported by DFT calculations.
引用
收藏
页码:929 / 931
页数:3
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