Fluorine-Enabled Cationic Gold Catalysis: Functionalized Hydration of Alkynes

被引：142
作者：
Wang, Weibo [1 ]
Jasinski, Jacek [2 ]
Hammond, Gerald B. [1 ]
Xu, Bo [1 ]
机构：
[1] Univ Louisville, Dept Chem, Louisville, KY 40292 USA
[2] Univ Louisville, Conn Ctr Renewable Energy Res, Louisville, KY 40292 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 40期
基金：
美国国家科学基金会;
关键词：
alkynes; fluorination; fluoroketones; gold; CROSS-COUPLING REACTIONS; ARYLBORONIC ACIDS; BOND FORMATION; ALKENES; KETONES; SPECTROSCOPY; CYCLIZATION; REACTIVITY; MECHANISM; XPS;
D O I：
10.1002/anie.201003593
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Fluorine makes it possible: A cationic fluorine-gold species generated by fluorination of a low-valence gold complex mediates the "functionalized hydration" of alkynes. A triple bond is used to install a carbonyl group and two new bonds on the a-carbon atom, all occurring in one pot, under mild conditions and in very good. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：7247 / 7252
页数：6
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