Fluorine-Enabled Cationic Gold Catalysis: Functionalized Hydration of Alkynes

被引：144

作者：

Wang, Weibo ^{[1
]}

Jasinski, Jacek ^{[2
]}

Hammond, Gerald B. ^{[1
]}

Xu, Bo ^{[1
]}

机构：

[1] Univ Louisville, Dept Chem, Louisville, KY 40292 USA

[2] Univ Louisville, Conn Ctr Renewable Energy Res, Louisville, KY 40292 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 40期

基金：

美国国家科学基金会;

关键词：

alkynes; fluorination; fluoroketones; gold; CROSS-COUPLING REACTIONS; ARYLBORONIC ACIDS; BOND FORMATION; ALKENES; KETONES; SPECTROSCOPY; CYCLIZATION; REACTIVITY; MECHANISM; XPS;

D O I：

10.1002/anie.201003593

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fluorine makes it possible: A cationic fluorine-gold species generated by fluorination of a low-valence gold complex mediates the "functionalized hydration" of alkynes. A triple bond is used to install a carbonyl group and two new bonds on the a-carbon atom, all occurring in one pot, under mild conditions and in very good. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7247 / 7252

页数：6

共 59 条

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[Anonymous], 2003, ANGEW CHEM

[2]

[Anonymous], ANGEW CHEM

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