Cyclopentenone formation by regioselective intermolecular coupling of trisubstituted alkenes, alkynes, and isocyanates

被引:25
作者
Takahashi, T [1 ]
Li, YZ
Tsai, FY
Nakajima, K
机构
[1] Hokkaido Univ, Catalysis Res Ctr, Kita Ku, Sapporo, Hokkaido 0600811, Japan
[2] Hokkaido Univ, Grad Sch Pharmaceut Sci, Kita Ku, Sapporo, Hokkaido 0600811, Japan
[3] Sci & Technol Corp, JST, CREST, Sapporo, Hokkaido 0600811, Japan
[4] Aichi Univ Educ, Dept Chem, Kariya, Aichi 4488542, Japan
关键词
D O I
10.1021/om001019d
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Zirconocenediethyl reacted with an alkyne, an, isocyanate, and a trisubstituted alkene with two electron-withdrawing groups in this order to give cyclopentenone derivatives in good yields after hydrolysis.
引用
收藏
页码:595 / 597
页数:3
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