Manganese(II)-azido/thiocyanato complexes of naphthylazoimidazoles:: X-ray structures of Mn(β-NaiEt)2(X)2 (β-NaiEt=1-ethyl-2-(naphthyl-β-azo)imidazole; X = N3-, NCS-)

被引：7

作者：

Das, D.

Chand, B. G.

Wu, J. S.

Lu, T.-H.

Sinha, C. ^{[1
]}

机构：

[1] Jadavpur Univ, Dept Chem, Inorgan Chem Sect, Kolkata 700032, W Bengal, India

[2] Natl Tsing Hua Univ, Dept Phys, Hsinchu 300, Taiwan

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2007年 / 842卷 / 1-3期

关键词：

naphthylazoimidazoles; manganese(II); azide; thiocyanate; X-ray structure; electrochemistry;

D O I：

10.1016/j.molstruc.2006.11.076

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Manganese(II)-naphthylazoimidazole complexes using N-3(-) and NCS- as counter ions are characterized as Mn(beta-NaiR)(2)(X)(2)(beta-NaiEt=1-alkyl-2-(naphthyl-beta-azo)imidazole; X = N-3(-), NCS-). The ligands are unsymmetric N(imidazole), N(azo) chelating agents. The microanalytical, spectral (FT-IR, UV-vis), magnetic (bulk moment and EPR) and electrochemical data establish the structure and composition of the complexes. The single crystal X-ray diffraction studies of Mn(beta-NaiEt)(2)(N-3)(2) and Mn(beta-NaiEt)(2)(NCS)(2)(beta-NaiEt=1-ethyl-2-(naphthyl-beta-azo)imidazole) have confirmed the three dimensional structure of the complexes. Cyclic voltammetry exhibits high potential Mn(III)/Mn(II) couple along with azo reductions. The EPR spectra show usual pattern. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：17 / 23

页数：7

共 26 条

[1] Nitro-ruthenium(II)-arylazoimidazoles:: synthesis, spectra, crystal structure and electrochemistry of dinitro-bis{1-alkyl-2-(arylazo)imidazole}ruthenium(II).: Nitro-nitroso derivatives and reactivity of the electrophilic {Ru-NO}6 system [J].