Polyvinyl alcohol thin film reinforced by green synthesized zirconia nanoparticles

被引:32
作者
Davar, F. [1 ]
Majedi, A. [2 ]
Mirzaei, A. [1 ]
机构
[1] Isfahan Univ Technol, Dept Chem, Esfahan 8415683111, Iran
[2] Univ Tehran, Sch Chem, Coll Sci, Tehran, Iran
关键词
Zirconia nanoparticles; Nanocomposite; PVA; Mechanical property; POLY(VINYL ALCOHOL); NANOCOMPOSITES; FABRICATION;
D O I
10.1016/j.ceramint.2018.07.167
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The focus of this work is to prepare polyvinyl alcohol (PVA) thin film reinforced by green synthesized zirconia nanoparticles. In order to do so, firstly, zirconia nanoparticles were synthesized by the rosemary extract-assisted sol-gel process as both template and stabilizing agents. The results showed that the as-obtained sample with zirconium salt to rosemary extract ratio of 1:4 had a semi-spherical morphology with the mean particle size of 12-17 nm. This nanoparticle was added as reinforcement with different ratios to the polyvinyl alcohol matrix. The mechanical property of the as-prepared nanocomposites revealed that the elastic modulus of 1 wt% ZrO2-PVA sample was about 5.5 times higher than pure PVA thin film.
引用
收藏
页码:19377 / 19382
页数:6
相关论文
共 43 条
[1]   Characterization of CeO2-ZrO2 mixed oxides.: Comparison of the citrate and sol-gel preparation methods [J].
Alifanti, M ;
Baps, B ;
Blangenois, N ;
Naud, J ;
Grange, P ;
Delmon, B .
CHEMISTRY OF MATERIALS, 2003, 15 (02) :395-403
[2]   Green synthesis of nanosilica by thermal decomposition of pine cones and pine needles [J].
Assefi, Mohammad ;
Davar, Fatemeh ;
Hadadzadeh, Hassan .
ADVANCED POWDER TECHNOLOGY, 2015, 26 (06) :1583-1589
[3]   Poly (vinyl alcohol) hydrogels for pH dependent colon targeted drug delivery [J].
Basak, Piyali ;
Adhikari, Basudam .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN MEDICINE, 2009, 20 :137-146
[4]   Polymer Nanocomposites-A Comparison between Carbon Nanotubes, Graphene, and Clay as Nanofillers [J].
Bhattacharya, Mrinal .
MATERIALS, 2016, 9 (04)
[5]   Crosslinked poly(vinyl alcohol) membranes [J].
Bolto, Brian ;
Tran, Thuy ;
Hoang, Manh ;
Xie, Zongli .
PROGRESS IN POLYMER SCIENCE, 2009, 34 (09) :969-981
[6]   Antimicrobial and antioxidant properties of rosemary and sage (Rosmarinus officinalis L. and Salvia officinalis L., lamiaceae) essential oils [J].
Bozin, Biljana ;
Mlmica-Dukic, Neda ;
Samojlik, Isidora ;
Jovin, Emilija .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2007, 55 (19) :7879-7885
[7]   Poly(vinyl alcohol) Nanocomposites Filled with Poly(vinyl alcohol)-Grafted Graphene Oxide [J].
Cheng, Henry Kuo Feng ;
Sahoo, Nanda Gopal ;
Tan, Yan Pei ;
Pan, Yongzheng ;
Bao, Hongqian ;
Li, Lin ;
Chan, Siew Hwa ;
Zhao, Jianhong .
ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (05) :2387-2394
[8]   Biodegradation of poly (vinyl alcohol) based materials [J].
Chiellini, E ;
Corti, A ;
D'Antone, S ;
Solaro, R .
PROGRESS IN POLYMER SCIENCE, 2003, 28 (06) :963-1014
[9]   Fundamentals, processes and applications of high-permittivity polymer matrix composites [J].
Dang, Zhi-Min ;
Yuan, Jin-Kai ;
Zha, Jun-Wei ;
Zhou, Tao ;
Li, Sheng-Tao ;
Hu, Guo-Hua .
PROGRESS IN MATERIALS SCIENCE, 2012, 57 (04) :660-723
[10]   Green Synthesis of ZnO Nanoparticles and Its Application in the Degradation of Some Dyes [J].
Davar, Fatemeh ;
Majedi, Ali ;
Mirzaei, Alireza .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2015, 98 (06) :1739-1746