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Hydrotalcite-supported gold-nanoparticle-catalyzed highly efficient base-free aqueous oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under atmospheric oxygen pressure
被引:384
作者:
Gupta, Navneet Kumar
[1
]
Nishimura, Shun
[1
]
Takagaki, Atsushi
[2
]
Ebitani, Kohki
[1
]
机构:
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi 9231292, Japan
[2] Univ Tokyo, Sch Engn, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
关键词:
AEROBIC OXIDATION;
CHEMICALS;
BIOMASS;
FRUCTOSE;
TRANSFORMATION;
SUGARS;
FUELS;
ALDOL;
D O I:
10.1039/c0gc00911c
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Green synthesis of 2,5-furandicarboxylic acid, one of the most important chemical building blocks from biomass, via oxidation of 5-hydroxymethylfurfural has been demonstrated using hydrotalcite-supported gold nanoparticle catalyst in water at 368 K under atmospheric oxygen pressure without addition of homogeneous base.
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页码:824 / 827
页数:4
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