Hydrotalcite-supported gold-nanoparticle-catalyzed highly efficient base-free aqueous oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under atmospheric oxygen pressure

被引:378
作者
Gupta, Navneet Kumar [1 ]
Nishimura, Shun [1 ]
Takagaki, Atsushi [2 ]
Ebitani, Kohki [1 ]
机构
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi 9231292, Japan
[2] Univ Tokyo, Sch Engn, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
关键词
AEROBIC OXIDATION; CHEMICALS; BIOMASS; FRUCTOSE; TRANSFORMATION; SUGARS; FUELS; ALDOL;
D O I
10.1039/c0gc00911c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Green synthesis of 2,5-furandicarboxylic acid, one of the most important chemical building blocks from biomass, via oxidation of 5-hydroxymethylfurfural has been demonstrated using hydrotalcite-supported gold nanoparticle catalyst in water at 368 K under atmospheric oxygen pressure without addition of homogeneous base.
引用
收藏
页码:824 / 827
页数:4
相关论文
共 50 条
  • [21] A novel platinum nanocatalyst for the oxidation of 5-Hydroxymethylfurfural into 2,5-Furandicarboxylic acid under mild conditions
    Siankevich, Sviatlana
    Savoglidis, Georgios
    Fei, Zhaofu
    Laurenczy, Gabor
    Alexander, Duncan T. L.
    Yan, Ning
    Dyson, Paul J.
    JOURNAL OF CATALYSIS, 2014, 315 : 67 - 74
  • [22] Atomic layer deposition of Pt nanoparticles on low surface area zirconium oxide for the efficient base-free oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
    Chen, Hao
    Shen, Jinshan
    Chen, Kequan
    Qin, Yong
    Lu, Xiuyang
    Ouyang, Pingkai
    Fu, Jie
    APPLIED CATALYSIS A-GENERAL, 2018, 555 : 98 - 107
  • [23] Efficient aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid on Ru/C catalysts
    Zheng, Lufan
    Zhao, Junqi
    Du, Zexue
    Zong, Baoning
    Liu, Haichao
    SCIENCE CHINA-CHEMISTRY, 2017, 60 (07) : 950 - 957
  • [24] On the mechanism of selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over supported Pt and Au catalysts
    Davis, Sara E.
    Zope, Bhushan N.
    Davis, Robert J.
    GREEN CHEMISTRY, 2012, 14 (01) : 143 - 147
  • [25] Aerobic oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid in water under mild conditions
    Liu, Bing
    Ren, Yongshen
    Zhang, Zehui
    GREEN CHEMISTRY, 2015, 17 (03) : 1610 - 1617
  • [26] Highly dispersed ruthenium nanoparticles on hydroxyapatite as selective and reusable catalyst for aerobic oxidation of 5-hydroxymethylfurfural to 2, 5-furandicarboxylic acid under base-free conditions
    Gao, Tianyu
    Yin, Yongxuan
    Fang, Wenhao
    Cao, Qiue
    MOLECULAR CATALYSIS, 2018, 450 : 55 - 64
  • [27] Functionalized Carbon Nanotubes for Biomass Conversion: The Base-Free Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid over Platinum Supported on a Carbon Nanotube Catalyst
    Zhou, Chunmei
    Deng, Weiping
    Wan, Xiaoyue
    Zhang, Qinghong
    Yang, Yanhui
    Wang, Ye
    CHEMCATCHEM, 2015, 7 (18) : 2853 - 2863
  • [28] Bimetallic Co-Mn catalyzed chemselective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid
    Zhu, Rui
    Gao, Fang
    Li, Xinglong
    MOLECULAR CATALYSIS, 2025, 580
  • [29] Au/Al2O3 - Efficient catalyst for 5-hydroxymethylfurfural oxidation to 2,5-furandicarboxylic acid
    Megias-Sayago, C.
    Lolli, A.
    Ivanova, S.
    Albonetti, S.
    Cavani, F.
    Odriozola, J. A.
    CATALYSIS TODAY, 2019, 333 : 169 - 175
  • [30] Heterogeneously-Catalyzed Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid with MnO2
    Hayashi, Eri
    Komanoya, Tasuku
    Kamata, Keigo
    Hara, Michikazu
    CHEMSUSCHEM, 2017, 10 (04) : 654 - 658