Hydrotalcite-supported gold-nanoparticle-catalyzed highly efficient base-free aqueous oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under atmospheric oxygen pressure

被引:384
作者
Gupta, Navneet Kumar [1 ]
Nishimura, Shun [1 ]
Takagaki, Atsushi [2 ]
Ebitani, Kohki [1 ]
机构
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi 9231292, Japan
[2] Univ Tokyo, Sch Engn, Dept Chem Syst Engn, Bunkyo Ku, Tokyo 1138656, Japan
关键词
AEROBIC OXIDATION; CHEMICALS; BIOMASS; FRUCTOSE; TRANSFORMATION; SUGARS; FUELS; ALDOL;
D O I
10.1039/c0gc00911c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Green synthesis of 2,5-furandicarboxylic acid, one of the most important chemical building blocks from biomass, via oxidation of 5-hydroxymethylfurfural has been demonstrated using hydrotalcite-supported gold nanoparticle catalyst in water at 368 K under atmospheric oxygen pressure without addition of homogeneous base.
引用
收藏
页码:824 / 827
页数:4
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