One-Pot Synthesis of [(C6F5)2BH2]- from C6F5MgBr/BH3•SMe2 and Its in Situ Transformation to Piers' Borane

被引：22

作者：

Schnurr, Anna ^{[1
]}

Samigullin, Kamil ^{[1
]}

Breunig, Jens M. ^{[1
]}

Bolte, Michael ^{[1
]}

Lerner, Hans-Wolfram ^{[1
]}

Wagner, Matthias ^{[1
]}

机构：

[1] Goethe Univ Frankfurt, Inst Anorgan & Analyt Chem, D-60438 Frankfurt, Main, Germany

来源：

ORGANOMETALLICS | 2011年 / 30卷 / 10期

关键词：

FRUSTRATED LEWIS PAIRS; PENTAFLUOROPHENYLBORON HALIDES; ACID CATALYSTS; REACTIVITY; HYDROBORATION; BIS(PENTAFLUOROPHENYL)BORANE; POLYMERIZATION; COCATALYSTS; ACTIVATION; CHEMISTRY;

D O I：

10.1021/om200186w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Depending on the crystallization procedure, the one-pot reaction between 2 C6F5MgBr, 1 BH3 center dot SMe2, and 1 Me3SiCl furnishes the hydridoborate salts [Mg-2(Et2O)(3)Br2Cl] [(C6F5)(2)BH2] and [Mg(Et2O)(2)][(C6F5)(2)BH2](2), both of which are convenient starting materials for the in situ generation of Piers' borane (C6F5)(2)BH.

引用

页码：2838 / 2843

页数：6

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